Coating compositions for electrode compositions and their methods of making

Patent metadata

Field	Value
Publication number	US-10020493-B2
Application number	US-201213645779-A
Country	US
Kind code	B2
Filing date	Oct 5, 2012
Priority date	Oct 5, 2012
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

Compositions and methods of making are provided for coated electrodes and batteries comprising the same. The compositions may comprise a base composition having an active material selected from the group consisting of LiCoO 2 , LiMn 2 O 4 , Li 2 MnO 3 , LiNiO 2 , LiMn 1.5 Ni 0.5 O 4 , LiFePO 4 , Li 2 FePO 4 F, Li 3 CoNiMnO 6 , Li(Li a Ni x Mn y Co z )O 2 , and mixtures thereof. The compositions may also comprise a coating composition that covers at least a portion of the base composition, wherein the coating composition comprises a non-metal or metalloid element. The methods of making comprise providing the base composition and a doped carbon coating composition, and mixing the coating composition with the base electrode composition at an elevated temperature in a flowing inert gas atmosphere. The coating composition may be a nitrogen-doped carbon composition a nitrogen doping element selected from the group consisting of: pyridine, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, 1-ethyl-3-methylimidazolium dicyanamide, and mixtures thereof.

First claim

What is claimed is:

1. An electrode for a battery comprising:
a cathode;
the cathode having a base composition having an active material capable of intercalating metal ions during a discharge cycle and deintercalating the metal ions during a charge cycle, wherein the active material is LiFePO 4 ; and
the cathode further having approximately 10-12% by weight of a nitrogen-doped carbon coating composition, the nitrogen-doped carbon coating composition covering at least a portion of the base composition and having a thickness of 5-50 nm, wherein the base composition does not contain nitrogen;
wherein the nitrogen-doped carbon coating composition comprises a nitrogen doping element derived from 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide.

2. The electrode of claim 1 , wherein the capacity is at least 10% greater at 3 C, or at least 30% greater at 5 C, when compared with a cathode having the same base composition without a coating composition.

3. The electrode of claim 1 wherein the nitrogen-doped carbon coating composition has a thickness of 10-15 nm.

4. The electrode of claim 1 , wherein the nitrogen-doped carbon coating composition is a non-oxide containing composition.

5. An electrode for a battery comprising:
a cathode;
the cathode having a base composition having an active material capable of intercalating metal ions during a discharge cycle and deintercalating the metal ions during a charge cycle, wherein the active material is LiFePO 4 ; and
the cathode further having approximately 10-12% by weight of a nitrogen-doped carbon coating composition, the nitrogen-doped carbon coating composition covering at least a portion of the base composition and having a thickness of 5-50 nm, the nitrogen-doped carbon coating composition is a non-oxide containing composition, and wherein the base composition does not contain nitrogen;
wherein the nitrogen-doped carbon coating composition comprises a bulk disordered graphite material; and
wherein the cathode has a capacity of at least 110 mAh/g at a rate of 3 C, or at least 98 mAh/g at a rate of 5 C,
wherein the nitrogen-doped carbon coating composition comprises a nitrogen doping element derived from 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide.

6. A battery comprising:
an anode having a base composition;
a cathode having a base composition with an active material capable of intercalating metal ions during a discharge cycle and deintercalating the metal ions during a charge cycle, wherein the active material is LiFePO 4 ;
the cathode further having approximately 12% by weight of a nitrogen-doped carbon coating composition that covers at least a portion of the base composition of the cathode and that has a thickness of 5-50 nm, the nitrogen-doped carbon coating composition is a non-oxide containing composition, and wherein the base composition does not contain nitrogen; and
an electrolyte capable of supporting reversible deposition and stripping of metal at the anode, and reversible intercalation and deintercalation of the metal at the cathode;
wherein the cathode has a capacity of at least 125 mAh/g at a rate of C/10, at least 120 mAh/g at a rate of 1 C, at least 110 mAh/g at a rate of 3 C, or at least 98 mAh/g at a rate of 5 C,
wherein the nitrogen-doped carbon coating composition comprises a nitrogen doping element derived from 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide.

7. The battery of claim 6 , wherein the capacity is at least 10% greater at 3 C, or at least 30% greater at 5 C, when compared with a cathode having the same base composition and an undoped carbon coating composition.

8. The battery of claim 6 , wherein the base composition of the anode comprises at least 90 wt. % lithium as the primary electrochemically active material of the anode.

9. The battery of claim 6 , wherein the base composition of the anode comprises mesoporous metal oxide microspheres, having (a) microspheres with an average diameter between 200 nm and 10 μm, and (b) mesopores on the surface and interior of the microspheres, wherein the mesopores have an average diameter between 1 nm and 50 nm and the microspheres have a surface area between 50 m 2 /g and 500 m 2 /g.

10. The battery of claim 6 , wherein the battery is selected from the group consisting of the following battery types: lithium-ion, aluminum-ion, magnesium-ion, sodium-ion, metal-air, and metal-sulfur, wherein the metal is lithium, aluminum, magnesium, zinc, or sodium.

11. The battery of claim 6 , wherein the battery is a lithium-ion battery.

12. The battery of claim 6 having an ability to charge from 0% to 50% of the full range capacity in 6 minutes, or an ability to charge from 0% to 33% of the full range capacity in 1 minute.

13. The battery of claim 6 having a functional discharge capacity of at least 90% of the initial discharge capacity after 100 cycles.

14. The battery of claim 6 , wherein the battery is used in a grid storage application, vehicle battery application, military application, portable electronic device application, medical device application, or standard cell size battery application.

15. The battery of claim 6 wherein the nitrogen-doped carbon coating composition has a thickness of 10-15 nm.

16. A method of forming a coated electrode comprising:
providing a cathode having a base electrode composition having an active material of LiFePO 4 ;
providing a nitrogen-doped carbon coating composition; and
mixing the coating composition with the base electrode composition at an elevated temperature in a flowing inert gas atmosphere,
wherein the nitrogen-doped carbon coating composition is a nitrogen-doped carbon composition having a nitrogen doping element from 1-ethyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imide,
wherein the cathode further having approximately 10-12% by weight of the nitrogen-doped carbon coating composition, the nitrogen-doped carbon coating composition covering at least a portion of the base electrode composition and having a thickness of 5-50 nm, wherein the base electrode composition does not contain nitrogen;
wherein the cathode has a capacity of at least 110 mAh/g at a rate of 3C, or at least 98 mAh/g at a rate of 5 C.

Assignees

• Ut Battelle Llc

Inventors

• Parans Paranthaman Mariappan
• Bridges Craig A
• Yoon Sukeun
• Sun Xiao-Guang
• Dai Sheng

Classifications

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/60

  of organic compounds · CPC title