Coated articles and method for making

Patent metadata

Field	Value
Publication number	US-10017844-B2
Application number	US-201514974755-A
Country	US
Kind code	B2
Filing date	Dec 18, 2015
Priority date	Dec 18, 2015
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

An article includes a substrate comprising a precipitate-strengthened alloy and a coating disposed over the substrate. The alloy comprises a) a population of gamma-prime precipitates, the population having a multimodal size distribution with at least one mode corresponding to a size of less than about 100 nanometers; or b) a population of gamma-double-prime precipitates having a median size less than about 300 nanometers. The coating comprises at least two elements, and further comprises a plurality of prior particles. At least a portion of the coating is substantially free of rapid solidification artifacts. Methods for fabricating the article and for processing powder useful for fabricating the article are also provided.

First claim

The invention claimed is:

1. An article comprising:
a substrate comprising a precipitate-strengthened alloy, the alloy comprising:
a) a population of gamma-prime precipitates, the population having a multimodal size distribution with at least one mode corresponding to a size of less than about 100 nanometers; or
b) a population of gamma-double-prime precipitates having a median size less than about 300 nanometers; and

a coating disposed over the substrate,
wherein the coating comprises (a) aluminum, chromium, and M, wherein M is at least one element selected from the group consisting of nickel, cobalt, and iron,
(b) a gamma phase and a beta phase, and a sigma phase where the sigma phase is less than 1 percent by volume of the coating, and (c) a plurality of prior particle boundaries, and wherein at least a portion of the coating is substantially free of rapid solidification artifacts.

2. The article of claim 1 , wherein at least about 10 volume percent of the coating is substantially free of the rapid solidification artifacts.

3. The article of claim 1 , wherein at least about 50 volume percent of the coating is substantially free of the rapid solidification artifacts.

4. The article of claim 1 , wherein the substrate comprises a nickel-based superalloy, a nickel-iron-based superalloy, or a cobalt-based superalloy.

5. The article of claim 1 , wherein the substrate comprises nickel-based superalloys.

6. The article of claim 1 , wherein the coating comprises at least about 5 weight percent aluminum.

7. The article of claim 1 , wherein the coating comprises a MCrAlX composition, wherein X comprises at least one element selected from the group consisting of yttrium, rhenium, tantalum, molybdenum, rare earth elements, hafnium, zirconium, silicon, and combinations thereof.

8. The article of claim 1 , wherein the coating comprises cobalt; from about 28 percent to about 35 percent nickel; from about 17 percent to about 25 percent chromium; from about 5 percent to about 15 percent aluminum; and from about 0.01 to about 1 percent yttrium.

9. The article of claim 1 , wherein the gamma phase is present at a concentration of at least about 25 volume percent of the coating.

10. The article of claim 9 , wherein the beta phase is present at a concentration of at least about 10 volume percent of the coating.

11. The article of claim 1 , wherein the coating is disposed in direct contact with the substrate at an interface, and wherein an interdiffusion zone between the coating and the substrate has a thickness of less than about 5 micrometers.

12. The article of claim 1 , wherein the article is a component of a gas turbine assembly.

13. The article of claim 1 , wherein the article is a turbine disk.

14. An article comprising:
a substrate comprising a nickel-based superalloy, the nickel-based superalloy comprising a population of gamma-prime precipitates, the population having a multimodal size distribution with at least one mode corresponding to a size of less than about 100 nanometers; and
a coating disposed over the substrate at an interface, the coating comprising
a) a MCrAlX composition,
b) a plurality of particle boundaries, and
c) a gamma phase of at least about 25 percent by volume of the coating, a beta phase in a range from about 10 percent to about 75 percent by volume of the coating, and a sigma phase where the sigma phase is less than 1 percent by volume of the coating;

wherein at least about 50 volume percent of the coating is substantially free of rapid solidification artifacts; and
wherein an interdiffusion zone extending from the interface into the substrate has a thickness of less than about 5 micrometers.

Assignees

• Gen Electric

Inventors

• Detor Andrew Joseph
• Ajdelsztajn Leonardo
• Bigelow Thomas Michael
• Didomizio Richard
• Emge Andrew William
• Ruud James Anthony
• Weimer Michael James

Classifications

• F05D2240/24

  for turbines · CPC title

• F01D5/08

  Heating, heat-insulating or cooling means {(specially adapted for radial flow machines or engines F01D5/04)} · CPC title

• B22F2301/20

  Refractory metals · CPC title

• B22F9/16

  using chemical processes · CPC title

• F05D2230/90

  Coating; Surface treatment · CPC title