Non-hazardous water-based polyurethane dispersion
US-12110373-B2 · Oct 8, 2024 · US
US10017663B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10017663-B2 |
| Application number | US-201314912630-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 22, 2013 |
| Priority date | Sep 22, 2013 |
| Publication date | Jul 10, 2018 |
| Grant date | Jul 10, 2018 |
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A polyurethane/acrylic hybrid dispersion comprising a polyurethane dispersion, acrylic monomers and ethylenically unsaturated phosphorus containing monomers. The weight ratio of the solid content of the polyurethane dispersion to the acrylic monomers and the ethylenically unsaturated phosphorus containing monomers is from 3:7 to 7:3. A process of making the polyurethane/acrylic hybrid dispersion.
Opening claim text (preview).
What is claimed is: 1. A polyurethane/acrylic hybrid dispersion comprising a polyurethane dispersion, acrylic monomers, a pigment, and ethylenically unsaturated phosphorus containing monomers, wherein the polyurethane/acrylic hybrid dispersion is made by polymerizing in a polyurethane dispersion, acrylic monomers, a pigment, and ethylenically unsaturated phosphorus containing monomers, wherein the weight ratio of the solid content of the polyurethane dispersion to that of the acrylic monomers and the ethylenically unsaturated phosphorus containing monomers is from 3:7 to 7:3. 2. The polyurethane/acrylic hybrid dispersion according to claim 1 wherein the ethylenically unsaturated phosphorus containing monomers are present from 0.3 wt. % to 2.0 wt. % based on the total combined weight of the acrylic monomers and the ethylenically unsaturated phosphorus containing monomers. 3. The polyurethane/acrylic hybrid dispersion according to claim 2 wherein the ethylenically unsaturated phosphorus containing monomers are present from 0.5 wt. % to 1.5 wt. % based on the total combined weight of the acrylic monomers and the ethylenically unsaturated phosphorus containing monomers. 4. The polyurethane/acrylic hybrid dispersion of claim 3 wherein the ethylenically unsaturated phosphorus containing monomers comprise phosphoethylmethacrylates. 5. The polyurethane/acrylic hybrid dispersion of claim 2 wherein the ethylenically unsaturated phosphorus containing monomers comprise phosphoethylmethacrylates. 6. The polyurethane/acrylic hybrid according to claim 1 wherein the ethylenically unsaturated phosphorus containing monomers are selected from phosphoalkyl (meth)acrylates, phosphoalkoxy (meth)acrylates, salts of phosphoalkyl (meth)acrylates, salts of phosphoalkoxy (meth)acrylates, and the mixture thereof. 7. The polyurethane/acrylic hybrid dispersion of claim 6 wherein the ethylenically unsaturated phosphorus containing monomers comprise phosphoethylmethacrylates. 8. The polyurethane/acrylic hybrid dispersion according to claim 1 wherein the weight ratio of the solid content of the polyurethane dispersion to that of the acrylic monomers and the ethylenically unsaturated phosphorus containing monomers is from 4:6 to 6:4. 9. The polyurethane/acrylic hybrid dispersion of claim 8 wherein the ethylenically unsaturated phosphorus containing monomers comprise phosphoethylmethacrylates. 10. The polyurethane/acrylic hybrid dispersion of claim 1 wherein the ethylenically unsaturated phosphorus containing monomers comprise phosphoethylmethacrylates. 11. A process of making a polyurethane/acrylic hybrid dispersion comprising polymerizing in a polyurethane dispersion, acrylic monomers, a pigment, and ethylenically unsaturated phosphorus containing monomers, wherein the weight ratio of the solid content of the polyurethane dispersion to that of the acrylic monomers and the ethylenically unsaturated phosphorus containing monomers is from 3:7 to 7:3. 12. The process according to claim 11 wherein the ethylenically unsaturated phosphorus containing monomers are present from 0.3 wt. % to 2.0 wt. % based on the total combined weight of the acrylic monomers and the ethylenically unsaturated phosphorus containing monomers. 13. The process according to claim 11 wherein the ethylenically unsaturated phosphorus containing monomers are selected from phosphoalkyl (meth)acrylates, phosphoalkoxy (meth)acrylates, salts of phosphoalkyl (meth)acrylates, salts of phosphoalkoxy (meth)acrylates, and the mixture thereof. 14. The process according to claim 11 wherein the weight ratio of the solid content of the polyurethane dispersion to that of the acrylic monomers and the ethylenically unsaturated phosphorus containing monomers is from 4:6 to 6:4.
Polyurethanes · CPC title
grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title
on to polymers provided for in C08G18/00 (C08F283/004 takes precedence) · CPC title
containing phosphorus · CPC title
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