Polyethylene-2,6-naphthalate composition with excellent blow moldability, and molded product thereof

Patent metadata

Field	Value
Publication number	US-10017629-B2
Application number	US-201515116682-A
Country	US
Kind code	B2
Filing date	Feb 19, 2015
Priority date	Feb 20, 2014
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

The object of the present invention is to provide a highly crystalline polyethylene-2,6-naphthalate composition by achieving high molecular weight of PEN, wherein the polyethylene-2,6-naphthalate composition has greatly improved blow moldability and provides molded products having excellent hue, excellent weathering resistance, and additionally excellent transparency. The above-mentioned problems can be solved by a polyethylene-2,6-naphthalate composition comprising a specific phosphoric acid which is a phosphorus compound, cobalt element derived from a cobalt compound, manganese element derived from a manganese compound, and antimony element derived from an antimony compound, wherein the content of each of the elements simultaneously satisfies the following expressions (1) to (4):

10≤Co≤30 mmol %  (1)

0.50≤P/Mn≤1.28  (2)

10≤Sb≤25 mmol %  (3)

0.60≤IV≤1.50 dL/g  (4).

First claim

The invention claimed is:

1. A polyethylene-2,6-naphthalate composition comprising a phosphorus compound represented by the following formula (I), cobalt element derived from a cobalt compound, manganese element derived from a manganese compound, and antimony element derived from an antimony compound, the content of each of the elements simultaneously satisfying the following expressions (1) to (4):

wherein R represents an alkyl group having 1 to 12 carbon atoms, an aryl group having 6 to 12 carbon atoms, or a benzyl group;
10≤Co≤30 mmol %  (1)

0.50≤P/Mn≤1.28  (2)

10≤Sb≤25 mmol %  (3)

0.60≤IV≤1.50 dL/g  (4)

in the expressions (1) to (4), Co, P, Mn, and Sb respectively represent the content of the cobalt element derived from the cobalt compound, the content of the phosphorus compound represented by the formula (I), the content of the manganese element derived from the manganese compound, and the content of the antimony element derived from the antimony compound, per mole of a dicarboxylic acid component constituting polyethylene-2,6-naphthalate in the polyethylene-2,6-naphthalate composition, and IV represents the intrinsic viscosity of the polyethylene-2,6-naphthalate composition; and
wherein the dicarboxylic acid component constituting polyethylene-2,6-naphthalate is only 2,6-naphthalene dicarboxylic acid.

2. The polyethylene-2,6-naphthalate composition according to claim 1 , wherein the intrinsic viscosity (IV) of the polyethylene-2,6-naphthalate composition satisfies the following expression (5):
0.80≤IV≤1.50 dL/g  (5).

3. The polyethylene-2,6-naphthalate composition according to claim 1 , wherein the content of the phosphorus compound represented by the general formula (I) is 10 to 50 mmol % per mole of the dicarboxylic acid component constituting polyethylene naphthalate.

4. A polyester molded product comprising the polyethylene-2,6-naphthalate composition according to claim 1 .

5. The polyester molded product according to claim 4 , wherein the polyester molded product is a direct blow molded product.

6. The polyester molded product according to claim 4 , wherein the polyester molded product is an injection blow molded product.

7. The polyester molded product according to claim 4 , wherein the polyester molded product is a hollow molded product.

Assignees

• Teijin Ltd

Inventors

• Tomonari Yasuhiko

Classifications

• C08K2003/0843

  Cobalt · CPC title

• C08K3/32

  Phosphorus-containing compounds · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• C08K3/02

  Elements · CPC title

• C08G2120/00

  Compositions for reaction injection moulding processes · CPC title