Monomer and polymer and compensation film and optical film and display device

Patent metadata

Field	Value
Publication number	US-10017456-B2
Application number	US-201615171453-A
Country	US
Kind code	B2
Filing date	Jun 2, 2016
Priority date	Jan 7, 2016
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

A monomer is represented by Chemical Formula 1:

wherein in Chemical Formula 1, X 1 and X 2 are independently O, C(═O), or C(═O)O, R 1 to R 10 are independently hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C3 to C20 cycloalkyl group, a substituted or unsubstituted C6 to C20 aryl group, a substituted or unsubstituted C3 to C20 heterocyclic group, a substituted or unsubstituted silyl group, a hydroxy group, a halogen, a nitro group, or a combination thereof, and n1 and n2 are independently an integer ranging from 0 to 3.

First claim

What is claimed is:

1. A monomer represented by Chemical Formula 1:

wherein in Chemical Formula 1,
X 1 and X 2 are independently O, C(═O), or C(═O)O,
R 1 to R 10 are independently hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C3 to C20 cycloalkyl group, a substituted or unsubstituted C6 to C20 aryl group, a substituted or unsubstituted C3 to C20 heterocyclic group, a substituted or unsubstituted silyl group, a hydroxy group, a halogen, a nitro group, or a combination thereof, and
n1 and n2 are independently an integer ranging from 0 to 3.

2. The monomer of claim 1 , wherein the monomer is represented by Chemical Formula 1-1 or 1-2:

wherein in Chemical Formula 1-1 and 1-2,
X 1 and X 2 are independently O, C(═O), or C(═O)O,
R 1 to R 10 are independently hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C3 to C20 cycloalkyl group, a substituted or unsubstituted C6 to C20 aryl group, a substituted or unsubstituted C3 to C20 heterocyclic group, a substituted or unsubstituted silyl group, a hydroxy group, a halogen, a nitro group, or a combination thereof, and
n1 and n2 are independently an integer ranging from 0 to 3.

3. The monomer of claim 1 , wherein the monomer is represented by one of Chemical Formula 1-1A to 1-2D:

wherein in Chemical Formula 1-1A to 1-2D,
X 1 and X 2 are independently O, C(═O), or C(═O)O.

4. A polymer comprising a structural unit derived from the monomer of claim 1 .

5. The polymer of claim 4 , wherein the structural unit is derived from a reaction product of the monomer with a carbonate or a derivative thereof.

6. A polymer comprising a first structural unit represented by Chemical Formula 3:

wherein in Chemical Formula 3,
X 1 and X 2 are independently O, C(═O), or C(═O)O,
R 1 to R 10 are independently hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C3 to C20 cycloalkyl group, a substituted or unsubstituted C6 to C20 aryl group, a substituted or unsubstituted C3 to C20 heterocyclic group, a substituted or unsubstituted silyl group, a hydroxy group, a halogen, a nitro group, or a combination thereof, and
n1 and n2 are independently an integer ranging from 0 to 3.

7. The polymer of claim 6 , wherein the first structural unit is represented by Chemical Formula 3-1 or 3-2:

wherein in Chemical Formula 3-1 and 3-2,
X 1 and X 2 are independently O, C(═O), or C(═O)O,
R 1 to R 10 are independently hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C3 to C20 cycloalkyl group, a substituted or unsubstituted C6 to C20 aryl group, a substituted or unsubstituted C3 to C20 heterocyclic group, a substituted or unsubstituted silyl group, a hydroxy group, a halogen, a nitro group, or a combination thereof, and
n1 and n2 are independently an integer ranging from 0 to 3.

8. The polymer of claim 6 , wherein the first structural unit is represented by one of Chemical Formula 3-1A to 3-2D:

wherein in Chemical Formula 3-1A to 3-2D,
X 1 and X 2 are independently O, C(═O), or C(═O)O.

9. The polymer of claim 6 , wherein the polymer further comprises a second structural unit represented by Chemical Formula 4:

wherein in Chemical Formula 4,
L 1 is a single bond, a substituted or unsubstituted C1 to C20 alkylene group, a substituted or unsubstituted C3 to C20 cycloalkylene group, a substituted or unsubstituted C6 to C20 arylene group, a substituted or unsubstituted C3 to C20 divalent heterocyclic group, O, C(═O), C(═O)O, SO 2 , or a combination thereof, and
R 11 and R 12 are independently hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C3 to C20 cycloalkyl group, a substituted or unsubstituted C6 to C20 aryl group, a substituted or unsubstituted C3 to C20 heterocyclic group, a substituted or unsubstituted silyl group, a hydroxy group, a halogen, a nitro group, or a combination thereof.

10. The polymer of claim 9 , wherein a mole ratio of the first structural unit and the second structural unit is about 0.1:99.9 to about 10.0:90.0.

11. The polymer of claim 9 , wherein a mole ratio of the first structural unit and the second structural unit is about 1:99 to about 5:95.

12. A compensation film comprising a polymer comprising a structural unit derived from the monomer of claim 1 .

13. The compensation film of claim 12 , wherein the structural unit is derived from a reaction product of the monomer with a carbonate or a derivative thereof.

14. The compensation film of claim 12 , wherein the compensation film is elongated in a uniaxial or biaxial direction.

15. A compensation film comprising a first polymer comprising a first structural unit represented by Chemical Formula 3:

wherein in Chemical Formula 3,
X 1 and X 2 are independently O, C(═O), or C(═O)O,
R 1 to R 10 are independently hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C3 to C20 cycloalkyl group, a substituted or unsubstituted C6 to C20 aryl group, a substituted or unsubstituted C3 to C20 heterocyclic group, a substituted or unsubstituted silyl group, a hydroxy group, a halogen, a nitro group, or a combination thereof, and
n1 and n2 are independently an integer ranging from 0 to 3.

16. The compensation film of claim 15 , wherein the first structural unit is represented by Chemical Formula 3-1 or 3-2:

wherein in Chemical Formula 3-1 and 3-2,
X 1 and X 2 are independently O, C(═O), or C(═O)O,
R 1 to R 10 are independently hydrogen, a

Assignees

• Samsung Electronics Co Ltd

Inventors

• Kim Changki
• Androsov Dmitry
• Tsuji Masashi
• Choi Hyunseok

Classifications

• C07C69/82 Primary

  Terephthalic acid esters · CPC title

• G02B5/30

  Polarising elements (light-modulating devices with active elements G02F1/00) · CPC title

• C08G64/045

  containing aliphatic unsaturation · CPC title

• G02B1/00

  Optical elements characterised by the material of which they are made; Optical coatings for optical elements · CPC title

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title