Ceramic matrix composites and methods of making the same

Patent metadata

Field	Value
Publication number	US-10017424-B2
Application number	US-201514958156-A
Country	US
Kind code	B2
Filing date	Dec 3, 2015
Priority date	Dec 4, 2014
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

An improved method of preparing ceramic matrix composites includes blending one or more ceramic powders with one or more paraffinic binders to form a slurry; introducing a ceramic fiber preform into a die or mold; heating the slurry to a temperature above the melting point of the one or more paraffinic binders to form a heated slurry; introducing the heated slurry into the die or mold, the heated slurry infiltrating the ceramic fiber preform to form a slurry infiltrated preform; cooling the die or mold below the solidification temperature of the paraffinic binder, thereby forming a solid component from the slurry infiltrated preform; removing the solid component from the die or mold; heating the solid component to a temperature whereby the paraffinic binder is removed; and densifying the solid component after removing the paraffinic binder, thereby forming the ceramic matrix composite.

First claim

The invention claimed is:

1. A method for preparing a ceramic matrix composite, the method comprising:
blending one or more ceramic powders with one or more paraffinic binders and phenolic resin to form a slurry;
introducing a ceramic fiber preform into a die or mold;
heating the slurry to a temperature above the melting point of the one or more paraffinic binders to form a heated slurry;
introducing the heated slurry into the die or mold, the heated slurry infiltrating the ceramic fiber preform to form a slurry infiltrated preform;
cooling the die or mold below the solidification temperature of the paraffinic binder, thereby forming a solid component from the slurry infiltrated preform;
removing the solid component from the die or mold;
heating the solid component to a temperature whereby the paraffinic binder is removed; and
densifying the solid component after removing the paraffinic binder, thereby forming the ceramic matrix composite,
wherein, prior to introducing the ceramic fiber preform into the die or mold, the ceramic fiber preform is rigidized.

2. The method of claim 1 , wherein the densifying is by melt infiltration.

3. The method of claim 1 , wherein the densifying is by polymer impregnation and pyrolysis.

4. The method of claim 1 , wherein the slurry comprises from about 20% to about 70% by volume of the one or more ceramic powders.

5. The method of claim 4 , wherein the slurry comprises from about 30% to about 80% by volume of the one or more paraffinic binders.

6. The method of claim 1 , wherein the slurry comprises from about 30% to about 80% by volume of the one or more paraffinic binders.

7. The method of claim 6 , wherein the one or more paraffinic binders are mixed with a surfactant and the phenolic resin to form a paraffinic binder mixture.

8. The method of claim 7 , wherein the surfactant comprises one or more saturated or unsaturated C12-C16 fatty acids.

9. The method of claim 8 , wherein the surfactant has a concentration in the paraffinic binder mixture of from about 1% to about 12% by weight.

10. The method of claim 7 , wherein the phenolic resin has a concentration in the paraffinic binder mixture of from about 5% to about 75% by weight.

11. The method of claim 1 , wherein the one or more ceramic powders are selected from the group consisting of silicon carbide (SiC), silicon/silicon carbide, and combinations thereof.

12. The method of claim 1 , wherein the one or more paraffinic binders are selected from the group consisting of paraffin wax, heavy mineral oil, and combinations thereof.

13. The method of claim 1 , wherein the ceramic fiber preform is in the form of a fabric with an interphase coating on fibers of the ceramic fiber preform.

14. The method of claim 1 , wherein the ceramic fiber preform is rigidized by chemical vapor infiltration (CVI).

15. The method of claim 1 , wherein the mold or die is configured for extra fill volume in excess of the volume of the ceramic fiber preform.

16. The method of claim 1 , wherein the heating to remove the paraffinic binder is to a temperature of at least about 600° C.

17. The method of claim 1 , wherein the phenolic resin is present at a concentration from about 5% to about 75% a total weight of the one or more paraffinic binders and the phenolic resin.

Assignees

• Rolls Royce Corp

Inventors

• Landwehr Sean Erin

Classifications

• C04B35/632

  Organic additives · CPC title

• C04B2235/5248

  Carbon, e.g. graphite · CPC title

• C04B2235/428

  Silicon · CPC title

• C04B2235/483

  Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes · CPC title

• C04B2235/602

  Making the green bodies or pre-forms by moulding · CPC title