Use of peracetic acid/hydrogen peroxide and peroxide-reducing enzymes for treatment of drilling fluids, frac fluids, flowback water and disposal water

Patent metadata

Field	Value
Publication number	US-10017403-B2
Application number	US-201313798311-A
Country	US
Kind code	B2
Filing date	Mar 13, 2013
Priority date	Mar 30, 2012
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

Compositions and methods for the use of peracid compositions having low to substantially no hydrogen peroxide for various water treatments, including oil- and gas-field operations, and/or other aseptic treatments are disclosed. In numerous aspects, peracetic acid is the preferred peracid and is treated with a peroxide-reducing agent to substantially reduce the hydrogen peroxide content. Methods for using the treated peracid compositions for treatment of drilling fluids, frac fluids, flow back waters and disposal waters are also disclosed for improving water condition, reducing oxidizing damage associated with hydrogen peroxide and/or reducing bacteria infestation.

First claim

What is claimed is:

1. A method of treating oil or gas field operation water sources comprising:
treating a percarboxylic acid composition with a peroxide-reducing agent to generate an antimicrobial composition, wherein said percarboxylic acid composition is added to the peroxide-reducing agent in solution; wherein the peroxide-reducing agent is a catalase enzyme and wherein said percarboxylic acid composition comprises a percarboxylic acid and hydrogen peroxide;
providing the antimicrobial composition to an oil or gas field operation water source in need of treatment to form a treated water source, wherein the treated water source comprises (i) up to about 1000 ppm catalase enzyme, (ii) substantially free of hydrogen peroxide; (iii) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; and (iv) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid, and
directing the treated water source into a subterranean environment or disposing of the treated water source having a minimized environmental impact,
wherein the peroxide-reducing agent reduces and/or eliminates hydrogen peroxide from said percarboxylic acid composition; and
wherein said water source in need of treatment comprises fresh water, pond water, sea water, drilling fluid water, fracking water, produced water, or combination thereof from an oil and gas operation.

2. The method of claim 1 , wherein the water source in need of treatment comprises produced water.

3. The method of claim 2 , wherein the water source is at least 1 wt-% produced water and wherein antimicrobial efficacy of the antimicrobial composition on the treated water source kills, destroys, removes and/or inactivates at least 10% of the microorganisms in the water source, compared to an untreated water source water source that does not contain produced water.

4. The method of claim 1 , wherein the treating of the percarboxylic acid composition with the peroxide-reducing agent to generate the antimicrobial composition is not a pretreatment step and occurs within the water source in need of treatment.

5. The method of claim 1 , wherein the treated water reduces corrosion caused by hydrogen peroxide and reduces microbial-induced corrosion, and wherein the antimicrobial composition does not interfere with any friction reducers, viscosity enhancers, other functional ingredients, or combinations thereof, found in the water source.

6. The method of claim 1 , wherein the percarboxylic acid stability is improved through the pretreatment step to minimize hydrogen peroxide concentration within the percarboxylic acid composition, and wherein the C 1 -C 22 carboxylic acid is from about 0.0001 wt-% to about 5.0 wt-%, and wherein the C 1 -C 22 percarboxylic acid is from about 0.0001 wt-% to about 5.0 wt-%.

7. The method of claim 1 , wherein the percarboxylic acid is peracetic acid and the carboxylic acid is acetic acid.

8. The method of claim 1 , wherein an acidulant is added to the water source in need of treatment before the addition of the antimicrobial composition to the water source.

9. A method of treating an oil or gas field operation water source comprising:
adding a percarboxylic acid composition and catalase enzyme to an oil or gas field operation water source to form a treated water source, wherein said treated water source comprises (i) less than about 1000 ppm of a catalase enzyme, (ii) substantially free of hydrogen peroxide; (iii) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; and (iv) from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid;
wherein the catalase enzyme reduces and/or eliminates hydrogen peroxide from said percarboxylic acid composition, the treated water source reduces corrosion caused by hydrogen peroxide and reduces microbial-induced corrosion, said water source in need of treatment comprises fresh water, pond water, sea water, drilling fluid water, fracking water, produced water, or combination thereof from an oil and gas operation, and wherein the antimicrobial composition does not interfere with friction reducers, viscosity enhancers, other functional ingredients found in the water source or combinations thereof.

10. The method of claim 9 , wherein the water source comprises produced water.

11. The method of claim 9 , wherein the water source is drilling fluid water.

12. The method of claim 9 , further comprising contacting the percarboxylic acid composition with the catalase enzyme, to generate a pretreated antimicrobial composition.

13. The method of claim 9 , further comprising the step of directing the treated water source into a subterranean environment or disposing of the treated water source having a minimized environmental impact.

14. The method of claim 9 , wherein the percarboxylic acid stability is improved through the reduction of hydrogen peroxide concentration as a result of the addition of the peroxide-reducing agent.

15. The method of claim 9 , wherein the percarboxylic acid is peracetic acid and the carboxylic acid is acetic acid.

16. The method of claim 9 , wherein the adding of the percarboxylic acid composition and the peroxide-reducing agent to the water source occurs on an at least every 5 day dosing cycle.

17. The method of claim 9 , wherein an acidulant is added to the water source in need of treatment before the addition of the percarboxylic acid and peroxide-reducing agent to the water source.

18. An aqueous water treatment composition with antimicrobial activity comprising:
a produced water source in an oil or gas operation;
from about 1 ppm to about 1000 ppm of a peroxide-reducing enzyme, wherein the enzyme is a catalase enzyme;
substantially free of hydrogen peroxide;
from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid; and
from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 percarboxylic acid,
wherein the aqueous water treatment composition does not interfere with friction reducers, viscosity enhances, other functional ingredients found in the water source or combinations thereof.

19. The composition of claim 18 , further comprising at least one polymer or copolymer for modifying fluid viscosity, friction reducer, and/or corrosion inhibition, wherein the catalase enzyme does not negatively interfere with the activity of the one or more polymer(s) or copolymer(s), and wherein the pH is less than about 9.

20. The composition of claim 18 , wherein the percarboxylic acid is peracetic acid and wherein the carboxylic acid is acetic acid, and wherein the produced water source is at least 1 wt-% of the composition.

21. The composition of claim 18 , wherein the produced water source is a slick water source.

22. An aqueous water treatment composition with antimicrobial activity comprising:
a produced water source in an oil and gas operation;
about 1 ppm to about 1000 ppm of a peroxide-reducing enzyme, wherein the enzyme is a catalase enzyme;
substantially free of hydrogen peroxide; and
from about 0.0001 wt-% to about 10.0 wt-% of a C 1 -C 22 carboxylic acid;
from about 0.0001 wt-% to about 20.0 wt-% of a single or mixed percarboxylic acid,
wherein the aqueous water treatment composition does not interfere with friction reducers, viscosity enhances, other functional ingredients found in the water source or combinations thereof.

23. The composition of claim 22 , wherein the composition further comprising at least one polymer or copolymer for modifying fluid vis

Assignees

• Ecolab Usa Inc

Inventors

• Keasler Victor
• De Paula Renato
• Li Junzhong
• Mcsherry David D
• Herdt Brandon
• Staub Richard

Classifications

• A01N37/16

  containing the group [IMAGE cpc-sch-A01N-0934.gif]; Thio analogues thereof · CPC title

• C02F1/70 Primary

  by reduction {(C02F1/4676 takes precedence)} · CPC title

• C02F1/76

  with halogens or compounds of halogens {(C02F1/4674 takes precedence)} · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• C09K2208/32

  Anticorrosion additives · CPC title