Polycrystalline diamond bodies incorporating fractionated distribution of diamond particles of different morphologies

Patent metadata

Field	Value
Publication number	US-10017390-B2
Application number	US-201615074092-A
Country	US
Kind code	B2
Filing date	Mar 18, 2016
Priority date	Mar 30, 2015
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

Diamond bodies and methods of manufacture are disclosed. Diamond bodies are formed from at least a bimodal, alternatively a tri-modal or higher modal, feedstock having at least one fraction of modified diamond particles with a fine particle size (0.5-3.0 μm) and at least one fraction of diamond particles with coarse particle size (15.0 to 30 μm). During high pressure—high temperature processing, fine particle sized, modified diamond particles in the first fraction preferentially fracture to smaller sizes while preserving the morphology of coarse particle sized diamond particles in the second fraction. Diamond bodies incorporating the two fractions have a microstructure including second fraction diamond particles dispersed in a continuous matrix of first fraction modified diamond particles and exhibit improved wear characteristics, particularly for wear associated with drilling of geological formations.

First claim

What is claimed is:

1. A method of making a diamond body, the method comprising:
forming a diamond feedstock including at least first fraction of modified diamond particles and a second fraction of diamond particles;
forming an assembly, wherein the assembly includes a layer of the diamond feedstock arranged in a refractory container; and
processing the assembly at elevated temperature and elevated pressure sufficient to sinter the diamond feedstock into the diamond body, the diamond body having a microstructure including second fraction diamond particles dispersed in a continuous matrix including first fraction modified diamond particles and a binder phase,
wherein, in the diamond feedstock, modified diamond particles in the first fraction have a D 50 value of particle sizes of about 0.1 μm to about 3.0 μm and diamond particles in the second fraction have a D 50 value of particle sizes of about 10.0 μm to about 40.0 μm,
wherein the modified diamond particles are more friable than the diamond particles such that, in the diamond body, the modified diamond particles in the first fraction have a D 50 value less than the D 50 value of particle sizes of the modified diamond particles in the first fraction in the diamond feedstock and the diamond particles in the second fraction have a D 50 value of particle sizes that is within about 95% of the D 50 value of the particles in the second fraction of the diamond feedstock,
wherein diamond particles in the second fraction have a surface roughness of less than about 0.5, and a sphericity of greater than about 0.6; and
wherein the modified diamond particles in the diamond feedstock are present in an amount sufficient such that there is no more than 10% diamond particle-to-diamond particle bonding between the particles of the second fraction in the diamond body.

2. The method of claim 1 , wherein the diamond feedstock has a bimodal distribution of particle sizes in which the D 50 value of particle sizes of the modified diamond particles in the first fraction is a first mode of the bimodal distribution and the D 50 value of particle sizes of the diamond particles in the second fraction is a second mode of a bimodal distribution.

3. The method of claim 2 , wherein, in the diamond feedstock, the D 50 value of particle sizes of the diamond particles in the second fraction is about 10.0 μm to about 20.0 μm, and wherein, in the diamond body, diamond particles in the second fraction have a D 50 value of particle sizes of about 10.0 μm to about 20.0 μm.

4. The method of claim 1 , wherein the first fraction of modified diamond particles in the diamond feedstock are present in the amount between about 20 vol. % and about 40 vol. %.

5. The method of claim 1 , wherein the diamond feedstock includes a third fraction of diamond particles or of modified diamond particles, and wherein, in the diamond feedstock, particles in the third fraction have a D 50 value of particle sizes intermediate to the D 50 value of particle sizes in the first fraction and the D 50 value of particle sizes in the second fraction.

6. The method of claim 5 , wherein the D 50 value of particle sizes intermediate to the D 50 value of particle sizes in the first fraction and the D 50 value of particle sizes in the second fraction is about 3 μm to about 10 μm.

7. The method of claim 5 , wherein, in the diamond feedstock, the D 50 value of particle sizes of the diamond particles in the second fraction is about 10.0 μm to about 20.0 μm, and wherein, in the diamond body, diamond particles in the second fraction have a D 50 value of particle sizes of about 9.0 μm to about 20.0 μm.

8. The method of claim 1 , wherein the diamond feedstock includes a third fraction of diamond particles,
wherein, in the diamond feedstock, diamond particles in the third fraction have a D 50 value of particle sizes of about 3.0 μm to about 6.0 μm,
wherein, in the diamond feedstock, the D 50 value of particle sizes of the diamond particles in the second fraction is about 15.0 μm to about 40.0 μm, and
wherein, in the diamond body, diamond particles in the second fraction have a D 50 value of particle sizes of about 14.0 μm to about 40.0 μm.

9. The method of claim 8 , wherein the diamond feedstock has the following composition:
less than about 10 vol. %, first fraction,
about 20 vol. % to about 40 vol. %, third fraction, and
balance, second fraction.

10. The method of claim 1 , wherein the elevated temperature and the elevated pressure sufficient to sinter the diamond feedstock into the diamond body are from about 4 GPa to about 12 GPa and from about 1200° C. to about 1600° C.

11. The method of claim 1 , wherein a majority of the reduction occurs while the pressure is increasing to the elevated pressure.

12. The method of claim 11 , wherein a majority of the reduction occurs up to a pressure of about 2 GPa.

13. The method of claim 1 , wherein a ratio of D 50 values of particle size of the modified diamond particles in the feedstock to D 50 values of particle size of the modified diamond particles in the diamond body is at least about 1.2.

14. A method of making a diamond body, the method comprising:
forming a diamond feedstock including at least first fraction of modified diamond particles and a second fraction of diamond particles;
forming an assembly, wherein the assembly includes a layer of the diamond feedstock arranged in a refractory container; and
processing the assembly at elevated temperature and elevated pressure sufficient to sinter the diamond feedstock into the diamond body, the diamond body having a microstructure including second fraction diamond particles dispersed in a continuous matrix including first fraction modified diamond particles and a binder phase,
wherein, in the diamond feedstock, modified diamond particles in the first fraction have a D 50 value of particle sizes of about 0.1 μm to about 3.0 μm and diamond particles in the second fraction have a D 50 value of particle sizes of about 10.0 μm to about 40.0 μm, and
wherein diamond particles in the second fraction have a surface roughness of less than about 0.5, and a sphericity of greater than about 0.6.

15. The method of claim 1 , wherein the assembly includes a substrate and the step of processing the assembly sinters the diamond feedstock into the diamond body and metallurgically bonds the diamond body to the substrate.

16. The method of claim 14 , wherein diamond particles in the second fraction have the surface roughness in a range from about 0.2 to less than about 0.5, and the sphericity of greater than about 0.667.

17. The method of claim 14 , wherein diamond particles in the second fraction have the sphericity of about 0.667 to about 0.9.

18. The method of claim 4 , wherein the first fraction of modified diamond particles in the diamond feedstock are present in the amount between about 25 vol. % and about 35 vol. %.

19. The method of claim 8 , wherein the diamond feedstock includes a third fraction of diamond particles,
wherein, in the diamond feedstock, the D 50 value of particle sizes of the diamond particles in the second fraction is about 30.0 μm to about 40.0 μm, and
wherein, in the diamond body, diamond particles in the second fraction have a D 50 value of particle sizes of about 28.0 μm to about 40.0 μm.

20. The method of claim 9 , wherein the diamond feedstock has the following composition:
about 2 vol. % to about 8 vol. % first fraction,
about 25 vol. % to about 35 vol. %, third fraction, and
greater than about

Assignees

• Diamond Innovations Inc
• Baker Hughes Inc
• Baker Hughes A Ge Co Llc

Inventors

• JOHNSON Alexanne
• Gledhill Andrew Dean
• Scott Danny Eugene
• Bird Marc William

Classifications

• B22F7/08

  with one or more parts not made from powder {(B22F7/062 takes precedence)} · CPC title

• C04B2235/5472

  Bimodal, multi-modal or multi-fraction · CPC title

• C04B35/52

  based on carbon, e.g. graphite · CPC title

• C01B32/25 Primary

  Diamond · CPC title

• C22C29/08

  based on tungsten carbide · CPC title