Base stock production using a high activity catalyst

Patent metadata

Field	Value
Publication number	US-10016747-B2
Application number	US-201514887492-A
Country	US
Kind code	B2
Filing date	Oct 20, 2015
Priority date	Nov 3, 2014
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

Methods are provided for using a dewaxing catalyst formed using at least two structure directing agents for production of a lubricant base stock. For example, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic production of lubricant base stocks. Additionally or alternately, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can provide improved aromatic saturation during processing of a feed for lubricant base stock production.

First claim

What is claimed is:

1. A method for processing a feed using a catalyst formed using a dominant structure directing agent and a secondary structure directing agent, comprising:
exposing a feedstock having a T5 boiling point of at least 400° F. (204° C.) to a catalyst comprising ZSM-48 crystals under effective dewaxing conditions to form a dewaxed effluent, at least a portion of the ZSM-48 crystals being crystallized from reaction mixture including a dominant structure directing agent cation, said dominant structure directing agent cation comprising diquat-6 cation, diquat-5 cation or a mixture of diquat-6 cation and a diquat-5 cation, and a secondary structure directing agent cation, an amount of secondary structure directing agent cation in the reaction mixture being at least 20 mole % of a combined amount of dominant structure directing agent cation and secondary structure directing agent cation in the reaction mixture, the ZSM-48 crystals having a molar ratio of SiO 2 to Al 2 O 3 of 65 to 120.

2. The method of claim 1 , wherein the catalyst has an alpha value of at least 125.

3. The method of claim 1 , wherein the catalyst has an alpha value of at least 150.

4. The method of claim 1 , wherein the catalyst further comprises a hydrogenation metal comprising Pt, Pd, Ni, W, Co, Mo, or a combination thereof, the amount of hydrogenation metal being 0.1 wt % to 20 wt %.

5. The method of claim 1 , wherein the catalyst further comprises a binder, a surface area of the binder in the bound catalyst being 150 m 2 /g or less.

6. The method of claim 1 , wherein the effective dewaxing conditions comprise a temperature of from 200 to 450° C., a hydrogen partial pressure of from 1.8 MPag to 34.6 MPag (250 psig to 5000 psig), and a hydrogen treat gas rate of from 35.6 m 3 /m 3 (200 SCF/B) to 1781 m 3 /m 3 (10,000 scf/B).

7. The method of claim 1 , wherein the secondary structure directing agent comprises tetramethyl ammonium hydroxide, tetraethyl ammonium hydroxide, tetrapropyl ammonium hydroxide, tetrabutyl ammonium hydroxide, or a combination thereof.

8. The method of claim 7 , wherein the secondary structure directing agent cation is tetraethyl ammonium.

9. The method of claim 1 , wherein a molar ratio of the amount of secondary structure directing agent to the amount of hydroxyl ions is at least 1:10.

10. The method of claim 1 , wherein the amount of secondary structure directing agent cation Q 2 is at least 25 mole % of the combined amount of dominant structure directing agent cation and secondary structure directing agent cation.

11. The method of claim 1 , wherein the ZSM-48 crystals are synthesized from a reaction mixture having a molar ratio of combined structure directing agent cation to SiO 2 in said reaction mixture of 0.01 to 0.20; a molar ratio of SiO 2 to Al 2 O 3 in said reaction mixture of 50 to 200; a molar ratio of water to SiO 2 in said reaction mixture of 1 to 500; a molar ratio of hydroxyl group concentration to SiO 2 in said reaction mixture is from 0.1 to 0.3; and a molar ratio of alkali metal, M, to SiO 2 in said reaction mixture is from 0.05 to 0.4.

12. The method of claim 1 , wherein at least 50 vol % of the as-synthesized ZSM-48 crystals have a fibrous morphology.

13. The method of claim 1 , wherein at least 50 vol % of the as-synthesized ZSM-48 crystals have a needle-like morphology.

14. The method of claim 1 , wherein the reaction mixture has a molar ratio of combined structure directing agent cation to SiO 2 in said reaction mixture of 0.01 to 0.05; a molar ratio of SiO 2 to Al 2 O 3 in said reaction mixture of 50 to 150; a molar ratio of water to SiO 2 in said reaction mixture of 1 to 500; a molar ratio of hydroxyl group concentration to SiO 2 in said reaction mixture is from 0.1 to 0.3; and a molar ratio of alkali metal, M, to SiO 2 in said reaction mixture is from 0.05 to 0.4.

15. The method of claim 14 , wherein the molar ratio of SiO 2 to Al 2 O 3 in said reaction mixture is 65 to 120.

16. The method of claim 1 , wherein the feedstock has a T5 boiling point of at least 700° F., a sulfur content of 100 wppm or less, or a combination thereof.

17. The method of claim 1 , further comprising separating the dewaxed effluent to form at least one dewaxed diesel boiling range fraction, at least one dewaxed lubricating base oil fraction, or a combination thereof.

18. The method of claim 1 , further comprising hydrofinishing the dewaxed effluent under effective hydrofinishing conditions, the hydrofinishing optionally being performed after separating the dewaxed effluent to form at least one dewaxed diesel boiling range fraction, at least one dewaxed lubricating base oil fraction, or a combination thereof.

19. The method of claim 1 , further comprising hydrotreating the feedstock under effective hydrotreating conditions prior to said exposing, hydrocracking the feedstock under effective hydrocracking conditions prior to said exposing, hydrofinishing the feedstock under effective hydrofinishing conditions prior to said exposing, or a combination thereof.

Assignees

• Zhang Lei
• Hantzer Sylvain
• Lai Wenyih F
• Mccarthy Stephen J
• Owens Tracie L
• Exxonmobil Res & Eng Co

Inventors

• Zhang Lei
• Hantzer Sylvain
• Lai Wenyih F
• Mccarthy Stephen J
• Owens Tracie L

Classifications

• C10G65/12

  including cracking steps and other hydrotreatment steps · CPC title

• C10G2400/10

  Lubricating oil · CPC title

• C10G2300/304

  Pour point, cloud point, cold flow properties · CPC title

• C10G45/62

  containing platinum group metals or compounds thereof · CPC title

• C10G2300/302

  Viscosity · CPC title