Multifunctional nanomaterials and methods of photothermal heating and catalysis using the same

Patent metadata

Field	Value
Publication number	US-10016745-B2
Application number	US-201615183222-A
Country	US
Kind code	B2
Filing date	Jun 15, 2016
Priority date	Jun 15, 2016
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

The present invention is directed to multifunctional nanomaterials for photothermal heating and catalytic applications. The present invention discloses a method of photothermally heating a solution. The present method also discloses a method of catalyzing a reaction. Both methods require a step of exposing a solution to at least one wavelength of the electromagnetic spectrum. A gold-iron oxide nanomaterial comprising an iron oxide substrate and discrete gold particles deposited on the substrate is also disclosed.

First claim

The invention claimed is:

1. A method of photothermally heating a solution, the method comprising
exposing the solution to at least one wavelength of light of the electromagnetic spectrum,
wherein the solution contains gold-iron oxide nanomaterials comprising an iron oxide substrate and discrete gold particles deposited on the iron oxide substrate,
wherein the iron oxide substrate comprises a nanotube, a nanoring, or mixtures thereof.

2. The method of claim 1 , wherein the at least one wavelength of light is in the visible light spectrum.

3. The method of claim 1 , wherein the at least one wavelength of light is in the infrared spectrum.

4. The method of claim 1 , wherein the at least one wavelength of light is in the ultraviolet spectrum.

5. The method of claim 1 , wherein the iron oxide substrate is a nanotube.

6. The method of claim 1 , wherein the iron oxide substrate is a nanoring.

7. The method of claim 1 , wherein the iron oxide substrate has an average outer diameter of from 5 nm to 500 nm.

8. The method of claim 1 , wherein the iron oxide substrate has an inner diameter of from 5 nm to 500 nm.

9. The method of claim 1 , wherein the iron oxide substrate has an average length of from 10 nm to 500 nm.

10. The method of claim 1 , wherein the iron oxide is Fe 2 O 3 .

11. The method of claim 1 , wherein the iron oxide has a maghemite crystal phase.

12. The method of claim 1 , wherein the iron oxide has a hematite crystal phase.

13. The method of claim 1 , wherein the gold particles have an average diameter of from 5 nm to 100 nm.

14. The method of claim 1 , wherein the gold particles are not agglomerated on the iron oxide substrate.

15. The method of claim 1 , wherein the gold-iron oxide nanomaterial has an average surface area of from 5 m 2 /g to 200 m 2 /g.

16. The method of claim 1 , wherein the iron oxide substrate of the gold-iron oxide nanomaterial has an average surface area of from 5 m 2 /g to 200 m 2 /g.

17. The method of claim 1 , wherein the gold particles of the gold-iron oxide nanomaterial have an average surface area of from 0.0001 m 2 /g to 5 m 2 /g.

18. The method of claim 1 , wherein the iron to gold atomic ratio of the gold-iron oxide nanomaterial is from 3 to 200.

19. The method of claim 1 , wherein the at least one wavelength is in a range of from 400 nm to 750 nm.

20. The method of claim 1 , wherein the solution is exposed for at least 3 minutes and the bulk temperature of the solution increases by at least 10° C.

21. The method of claim 1 , wherein if the solution is exposed to a wavelength of from 500 to 600 nm for at least 5 minutes, the bulk temperature of the solution increases by at least 10° C.

22. The method of claim 1 , wherein the solution is an aqueous solution.

23. The method of claim 1 , wherein the solution further comprises at least one reactant, reagent, or any combination thereof.

24. The method of claim 23 , wherein the method further comprises a method of catalyzing a reaction.

Assignees

• Savannah River Nuclear Solutions Llc

Inventors

• Hunyadi Murph Simona E
• Larsen George K

Classifications

• B01J23/8906 Primary

  Iron and noble metals · CPC title

• C07C213/02

  by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups · CPC title

• B01J35/023

  Operations & Transport · mapped topic

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/10

  Infrared [IR] · CPC title