Method for producing metal oxide compositions and coated substrates

Patent metadata

Field	Value
Publication number	US-10016744-B2
Application number	US-201313859915-A
Country	US
Kind code	B2
Filing date	Apr 10, 2013
Priority date	Aug 24, 2006
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

The present invention generally relates to a process for making a metal oxide composition for use in removing contaminants from streams. A process of the present disclosure comprises contacting a metal salt with an aqueous solvent to form a metal salt mixture and reacting the metal salt mixture and a metal powder without the addition of heat. The present invention also relates to a process for making a coated metal oxide substrate.

First claim

What is claimed is:

1. A process for making a metal oxide composition for use in removing contaminants from fluid streams, the process comprising:
a. contacting a metal salt with an aqueous solvent from about 5 seconds to about 10 minutes to form a metal salt mixture, wherein the ratio of solvent to metal salt is from about 20:1 to about 1:20 by weight and the amount of solvent is such that a slurry or solution is not formed; and,
b. reacting a sufficient amount of the metal salt mixture and a metal powder for about 15 minutes to about 24 hours, at ambient conditions to initiate an oxidizing reaction between the metal powder and the metal salt mixture, wherein the ratio of metal powder to metal salt mixture is from about 7:1 to about 15:1, and wherein the oxidizing reaction substantially proceeds to form a metal oxide composition that is a free flowing, non-clumping powder comprising from at least 5% to more than 95% by weight metal oxide capable of removing contaminants from fluid streams.

2. The process of claim 1 , wherein the metal salt is selected from the group consisting of metal chloride, carbonate, sulfate, acetate, nitrate, chelate, phosphate, oxide, and combinations thereof.

3. The process of claim 2 wherein the metal salt is selected from the group consisting of: copper chloride, copper chloride dihydrate, ferric chloride dihydrate, sodium chloride dehydrate, iron chloride, sodium chloride, nickel chloride, manganese chloride, magnesium chloride, copper sulfate, iron sulfate, zinc sulfate, nickel sulfate, manganese sulfate, magnesium sulfate, zinc phosphate, nickel phosphate, iron phosphate, aluminum phosphate, copper nitrate, nickel nitrate, manganese nitrate, zinc nitrate, magnesium phosphate, and combinations thereof.

4. The process of claim 1 , wherein the aqueous solvent is selected from the group consisting of water and an alcohol/water mixture.

5. The process of claim 1 , wherein the alcohol is selected from the group consisting of glycol and isopropanol.

6. The process of claim 1 , wherein the metal salt and the aqueous solvent are contacted for from 5 seconds to 10 minutes.

7. The process of claim 1 , wherein the metal powder is selected from the group 2A, 3B, 4B, 5B, 6B, 7B, 8, 1B, 2B, 3A, 4A, 5A metals, rare earth metals, metal oxides, and combinations thereof.

8. The process of claim 1 , wherein the metal powder is selected from the group consisting of iron powder, zinc powder, tin powder, aluminum powder, antimony powder, magnesium powder, titanium powder, manganese powder, chromium powder, nickel powder, cobalt powder, platinum powder, metal oxides and combinations thereof.

9. The process of claim 1 , wherein the metal powder further comprises at least one additive.

10. The process of claim 9 , wherein the additive is selected from the group consisting of coconut coir, activated carbon, and combinations thereof.

11. The process of claim 1 , wherein the metal salt mixture and the metal powder are reacted for from 15 minutes to 24 hours.

12. The process according to claim 1 , wherein the resultant metal oxide composition is ready for use without further processing or drying.

13. A process for making a metal oxide composition for use in removing contaminants from streams, the process comprising:
a. contacting a metal salt with an aqueous solvent for 5 seconds to 10 minutes to form a metal salt mixture, wherein the ratio of solvent to metal salt is from about 20:1 to about 1:20 by weight and the amount of solvent is such that a solution or slurry is not formed; and,
b. reacting a sufficient amount of the metal salt mixture and a metal powder for 15 minutes to 24 hours at ambient conditions to initiate an oxidizing reaction between the metal powder and the metal salt mixture, wherein the ratio of metal powder to metal salt mixture is from about 7:1 to about 15:1, wherein the oxidizing reaction substantially proceeds to form a metal oxide composition that is a free flowing, non-clumping powder comprising from at least 5% to more than 95% by weight metal oxide, wherein the metal oxide composition reacts with contaminants in a stream, and wherein the contaminants are substantially removed from the stream.

14. The process of claim 13 , wherein the stream is selected from the group consisting of gas stream or fluid stream.

15. A process for making a metal oxide composition for use in removing contaminants from fluid streams, the process comprising:
a. contacting a metal salt with an aqueous solvent for 5 seconds to 10 minutes to form a metal salt mixture, wherein the ratio of solvent to metal salt is from about 20:1 to about 1:20 by weight and the amount of solvent is such that a solution or slurry is not formed; and,
b. reacting a sufficient amount of the metal salt mixture and a metal powder for 15 minutes to 24 hours at ambient conditions to initiate an oxidizing reaction between the metal powder and the metal salt mixture, wherein the ratio of metal powder to metal salt mixture is from about 7:1 to about 15:1, wherein the oxidizing reaction substantially proceeds to form a metal oxide composition that is a free flowing, non-clumping powder comprising from at least 5% to more than 95% by weight metal oxide, wherein the metal oxide composition reacts with contaminants in a stream, and wherein the contaminants are substantially removed from the stream; and,
c. placing the metal oxide composition in a reaction vessel; and,
d. contacting the metal oxide composition with a contaminated stream, wherein the stream is a gas or fluid stream.

16. A process for making a metal oxide composition for use in removing contaminants from fluid streams, the process comprising:
a. contacting a metal salt with an aqueous solvent for 5 seconds to 10 minutes to form a metal salt mixture, wherein the ratio of solvent to metal salt is from about 20:1 to about 1:20 by weight and the amount of solvent is such that a slurry or solution is not formed; and,
b. reacting a sufficient amount of the metal salt mixture and a metal powder for 15 minutes to 24 hours at ambient conditions to initiate an oxidizing reaction between the metal powder and the metal salt mixture, wherein the ratio of metal powder to metal salt mixture is from about 7:1 to about 15:1, wherein the oxidizing reaction substantially proceeds to form a metal oxide composition that is a free flowing, non-clumping powder comprising from at least 5% to more than 95% by weight metal oxide;
c. contacting the metal oxide composition with a stream;
d. reacting the metal oxide composition with contaminants in the stream; and,
e. removing the contaminants substantially from the stream.

17. A process for making a metal oxide composition, the process comprising:
a. contacting a metal salt with an aqueous solvent for 5 seconds to 10 minutes to form a metal salt mixture, wherein the ratio of solvent to metal salt is from about 20:1 to about 1:20 by weight and the amount of solvent is such that a slurry or solution is not formed; and,
b. reacting a sufficient amount of the metal salt mixture and a metal powder for 15 minutes to 24 hours at ambient conditions to initiate an oxidizing reaction between the metal powder and the metal salt mixture, wherein the ratio of metal powder to metal salt mixture is from about 7:1 to about 15:1, and wherein the oxidizing reaction substantially proceeds to form a metal oxide that is a free flowing, non-clumping powder composition comprising from at least 5% to more than 95% by weight metal oxide capable of use in removing contaminants from fluid streams,
wherein the metal oxide composition comprises

Assignees

• Scranton Delbert C
• Axens

Inventors

• Scranton Delbert C

Classifications

• C09C1/0021

  comprising a core coated with only one layer having a high or low refractive index · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• C01G1/02

  Oxides · CPC title

• B01J37/0236

  Drying, e.g. preparing a suspension, adding a soluble salt and drying · CPC title

• C09C1/42

  Clays · CPC title