Material for neutralising and/or hardening liquids, a method for producing same, and uses
US-2024293793-A1 · Sep 5, 2024 · US
US10016742B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10016742-B2 |
| Application number | US-201515123602-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 12, 2015 |
| Priority date | Mar 7, 2014 |
| Publication date | Jul 10, 2018 |
| Grant date | Jul 10, 2018 |
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The invention related to a material that can stably hold an imide anion (NH 2− ) therein even in the atmosphere or in a solvent, and a method for synthesizing the material and a use of the material. A mayenite-type compound into which imide anions are incorporated at a concentration of 1×10 18 cm −3 or more are provided. The mayenite-type compound can be produced by heating a mayenite-type compound including electrons or free oxygen ions in a cage thereof, in liquefied ammonia at 450 to 700° C. and at a pressure of 30 to 100 MPa. The compound has properties such that active imide anions can be easily incorporated into the compound and the active imide anions can be easily released in the form of ammonia from the compound, and the compound has chemical stability.
Opening claim text (preview).
The invention claimed is: 1. A mayenite-type compound, wherein imide anions are incorporated into the mayenite-type compound at a concentration of 1×10 18 cm −3 or more, and the mayenite-type compound is a compound having the same type of crystal structure as a crystal structure of mayenite. 2. A method for producing the mayenite-type compound according to claim 1 comprising: heating a mayenite-type compound including electrons or free oxygen ions in a cage thereof, in liquefied ammonia at 450° C. to 700° C. and at a pressure of 30 to 100 MPa. 3. An imide anion supplying material comprising the mayenite-type compound according to claim 1 . 4. An ammonia supplying material comprising the mayenite-type compound according to claim 1 . 5. The mayenite-type compound according to claim 1 , wherein imide anions are incorporated into the mayenite-type compound at a concentration of 1×10 18 cm −3 to 1.1×10 21 cm −3 . 6. The method according to claim 2 , comprising heating a mayenite-type compound including electrons or free oxygen ions in a cage thereof, in liquefied ammonia at 450° C. to 650° C. and at a pressure of 30 to 100 MPa.
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