Optical film, method of manufacturing the same, polarizing plate and liquid crystal display device

Patent metadata

Field	Value
Publication number	US-10012770-B2
Application number	US-201514812477-A
Country	US
Kind code	B2
Filing date	Jul 29, 2015
Priority date	Feb 1, 2013
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

There is provided an optical film comprising a layer formed on a base film by curing a curable composition containing the specific component (A) in an amount of 50 to 99% by mass and the specific component (B) in an amount of 1 to 50% by mass, based on the total solid content of the curable composition when the total solid content of the curable composition is set to 100% by mass.

First claim

The invention claimed is:

1. An optical film comprising:
a base film formed from a cellulose acylate or a (meth)acrylic polymer having at least one of a lactone ring structure, an anhydrous glutaric acid ring structure and a glutarimide ring structure in its main chain, and
a layer formed on the base film by curing a curable composition containing the following (A) in an amount of 50 to 99% by mass and the following (B) in an amount of 1 to 50% by mass, based on the total solid content of the curable composition when the total solid content of the curable composition is set to 100% by mass:
(A) at least one of a compound having a cycloaliphatic hydrocarbon group and an ethylenically unsaturated double bond and a compound having a fluorene ring and an ethylenically unsaturated double bond, and
(B) a rosin compound which has an acid number from 280 to 400 mgKOH/g,
wherein when the layer containing (A) and (B) has a film thickness of 10 μm, a converted moisture permeability of the layer containing (A) and (B) ranges from 5.0 to 100 g/m 2 /day,
the moisture permeability is a value obtained according to a method described in JIS Z-0208 after the lapse of 24 hours under a temperature of 40 ° C. and a relative humidity of 90%, the moisture permeability of the layer containing (A) and (B) and having a film thickness of 10 pm is calculated by the following Equation (2):
J b ×d b /10  Equation (2)

in Equation (2),
J b represents the moisture permeability of the layer when the optical film is separated into the base film and the layer containing (A) and (B), and
d b [μm] is a film thickness of the low moisture-permeable layer.

2. The optimal film as claimed in claim 1 ,
wherein the cycloaliphatic hydrocarbon group is represented by the following Formula (I):

in Formula (I),
each of L and L′ independently represents a di- or higher-valent linking group, and
n represents an integer of 1 to 3.

3. The optical film as claimed in claim 1 ,
wherein the rosin compound is at least one rosin compound selected from a rosin, a hydrogenated rosin, an acid-modified rosin, and an esterified rosin.

4. The optical film as claimed in claim 3 ,
wherein the rosin compound is an acid-modified rosin.

5. The optical film as claimed in claim 1 ,
wherein the optical film has a moisture permeability of 5.0 to 100 g/m 2 /day,
the moisture permeability of the optical film is a value obtained according to a method described in JIS Z-0208 after the lapse of 24 hours under a temperature of 40° C. and a relative humidity of 90%.

6. The optical film as claimed in claim 1 ,
wherein a moisture permeability of the layer containing (A) and (B) is from 5.0 to 100 g/m 2 /day,
the moisture permeability is a value obtained according to a method described in JIS Z-0208 after the lapse of 24 hours under a temperature of 40° C. and a relative humidity of 90%, and the moisture permeability of the layer containing (A) and (B) is calculated by the following Equation (1):
1/ J f =1/ J s +1/ J b   Equation (1)

in Equation (1),
J b represents the moisture permeability of the layer when the optical film is separated into the base film and the layer containing (A) and (B), the moisture permeability of the optical film is denoted as J f and the moisture permeability of the base film is denoted as J s .

7. The optical film as claimed in claim 1 , further comprising a hard coat layer on the layer containing (A) and (B).

8. A polarizing plate comprising:
a polarizer, and
an optical film claimed in claim 1 as a protective film for the polarizer.

9. A liquid crystal display device comprising:
a liquid crystal cell and
the polarizing plate claimed in claim 8 , which is disposed on at least one side of the liquid crystal cell,
wherein the optical film is arranged such that it becomes the outermost surface layer.

10. A method of manufacturing an optical film, comprising:
forming a base film from a cellulose acylate or a (meth)acrylic polymer having at least one of a lactone ring structure, an anhydrous glutaric acid ring structure and a glutarimide ring structure in its main chain, and
forming a layer on the base film by curing a curable composition containing the following (A) and (B):
(A) at least one of a compound having a cycloaliphatic hydrocarbon and an ethylenically unsaturated double bond and a compound having a fluorene ring and an ethylenically unsaturated double bond in an amount of 50 to 99% by mass, based on the total solid content of the curable composition when the total solid content of the curable composition is set to 100% by mass,
(B) a rosin compound having an acid number from 280 to 400 mgKOH/g, in an amount of 1 to 50% by mass, based on the total solid content of the curable composition,
wherein when the layer containing (A) and (B) has a film thickness of 10 μm, a converted moisture permeability of the layer containing (A) and (B) ranges from 5.0 to 100 g/m 2 /day,
the moisture permeability is a value obtained according to a method described in JIS Z-0208 after the lapse of 24 hours under a temperature of 40 ° C. and a relative humidity of 90%, the moisture permeability of the layer containing (A) and (B) and having a film thickness of 10 pm is calculated by the following Equation (2):
J b ×d b /10  Equation (2)

in Equation (2),
J b represents the moisture permeability of the layer when the optical film is separated into the base film and the layer containing (A) and (B), and
d b [μm] is a film thickness of the low moisture-permeable layer.

Assignees

• Fujifilm Corp

Inventors

• Fukuda Kenichi
• Asahi Miho
• Nozoe Yutaka

Classifications

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• Y10T428/31848

  Next to cellulosic · CPC title

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• C08J2435/02

  Characterised by the use of homopolymers or copolymers of esters (C08J2435/06, C08J2435/08 take precedence) · CPC title

• C08J2333/12

  Homopolymers or copolymers of methyl methacrylate · CPC title