Vacuum insulating glass (VIG) unit with metallic peripheral edge seal and/or methods of making the same

Patent metadata

Field	Value
Publication number	US-10012019-B2
Application number	US-201514789444-A
Country	US
Kind code	B2
Filing date	Jul 1, 2015
Priority date	Dec 31, 2013
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

Certain example embodiments relate to vacuum insulating glass units having edge seals formed in connection with solder alloys that, when reactively reflowed, wet metallic coatings pre-coated on the glass substrates' perimeters, and/or associated methods. The alloys may be based on materials that form seals at temperatures that will not de-temper glass and/or decompose a laminate, and/or remain hermetic and lack porous structures in their bulks. Example alloys may be based on inter-metallics of Sn and one or more materials selected from post-transition metals or metalloids; Zintl anions (e.g., In, Bi, etc.) from Group 13, 14, 15, or 16; and transition metals (e.g., Cu, Ag, Ni, etc.); and excludes Pb. Thin film coatings in certain example embodiments work with the solder material to form robust and durable hermetic interfaces. Because low temperatures are used, certain example embodiments can use compliant and visco-elastic spacer technology based on lamellar structures and/or the like.

First claim

What is claimed is:

1. A method of making a vacuum insulating glass (VIG) unit, the method comprising:
forming a first layer stack around peripheral edges of a first major surface of a first substrate;
forming a second layer stack around peripheral edges of a first major surface of a second substrate;
the first and second multi-layer stacks being formed via high velocity wire combustion (HVWC) and/or high velocity oxy-fuel (HVOF) deposition which directs molten particles toward the corresponding substrate, and each multi-layer stack including, in order moving away from the first major surfaces of the substrates on which they are formed, a layer comprising silicon nitride, a layer comprising nickel, and a layer comprising silver;
placing a plurality of spacers on the first major surface of the first substrate;
placing a solid solder alloy pre-form over and contacting the first layer stack;
bringing together the first and second substrates such that the first major surfaces thereof face one another and form a subassembly;
forming an edge seal by reactively reflowing the solid solder alloy pre-form to cause material from the first and second layer stacks to diffuse into the solder alloy material, and vice versa; and
following the formation of the edge seal, which then includes inter-metallic compounds, evacuating a cavity formed between the first and second substrates in making the VIG unit.

2. The method of claim 1 , wherein the first and second substrates are glass substrates, and the first major surfaces thereof are air side glass surfaces.

3. The method of claim 2 , wherein the first and second layer stacks are formed directly on and contacting the first surfaces of the first and second substrates, respectively.

4. The method of claim 1 , wherein the layers comprising nickel comprise NiCr.

5. The method of claim 1 , wherein the first and second layer stacks are formed in an at least partially reducing atmosphere.

6. The method of claim 1 , further comprising burnishing the first and second layer stacks to remove unwanted oxide, nitride, and/or carbon content therefrom, prior to formation of the edge seal.

7. The method of claim 1 , wherein the stacks are formed via a high velocity wire combustion (HVWC) apparatus that accepts wire feed stock.

8. The method of claim 7 , further comprising providing hydrogen and oxygen to the HVWC apparatus in performing the activated energetic spray deposition.

9. The method of claim 7 , wherein the HVWC apparatus combusts the wire feed stock and generates particles that are accelerated to a velocity of 150-400 m/s in performing the activated energetic spray deposition.

10. The method of claim 1 , wherein the stacks are formed via a high velocity oxy-fuel apparatus.

11. The method of claim 1 , further comprising controlling the deposition to form layers such that each of the layers in the layer stacks, and the layer stacks in their respective entireties, have porosities of less than 2%.

12. The method of claim 1 , further comprising controlling the deposition to form layers such that each of the layers in the layer stacks has an adhesion or bond strength of at least 10 MPa and such that each of the layer stacks has an adhesion or bond strength of at least 20 MPa.

13. The method of claim 1 , further comprising controlling the deposition to form layers such that each of the layers in the layer stacks, and the layer stacks in their respective entireties, have an RMS roughness (Ra) of less than 2 microns.

14. The method of claim 1 , wherein the substrates reach temperatures of no more than 150 degrees C. during the depositions.

15. The method of claim 1 , wherein the layers comprising nickel are deposited to a thickness of 10-20 microns and/or the layers comprising silver are deposited to a thickness of 15-25 microns.

16. The method of claim 1 , wherein the substrates reach temperatures sufficiently high to cause significant degasing of the substrates and significant removal of water from the substrate, but sufficiently low to prevent the loss of temper strength.

17. The method of claim 1 , wherein the solid solder alloy pre-form is a solder wire pre-form.

18. The method of claim 1 , wherein the solid solder alloy pre-form comprises either Sn, Ag, and Cu, or In and Ag.

19. The method of claim 1 , wherein the forming of the edge seal further comprises heating the subassembly to a peak temperature of less than 390 degrees C.

20. The method of claim 1 , wherein the forming of the edge seal further comprises heating the subassembly to a peak temperature of that is at least as high as, but no more than 30 degrees C. higher than, an isopleth temperature of the solid solder alloy pre-form.

21. The method of claim 1 , wherein the first and second layer stacks are formed immediately after the respective substrates on which they are deposited are cooled.

22. The method of claim 1 , wherein at least one of the substrates is a glass substrate that is heat treated.

23. The method of claim 1 , wherein at least one of the substrates is a glass substrate that is thermally tempered.

24. The method of claim 23 , wherein each said glass substrate that is thermally tempered loses no more than 10% temper strength as a result of the activated energetic spray deposition and the evacuating, combined.

25. A method of making a vacuum insulating glass (VIG) unit, the method comprising:
forming multilayer coatings around peripheral edges of first major surfaces of first and second substrates, each said coating including, in order moving away from the respective substrate on which it is formed, a layer comprising silicon nitride, a layer comprising nickel, and a layer comprising silver, each said coating being selectively deposited using a high velocity wire combustion (HVWC) or high velocity oxy-fuel (HVOF) apparatus in an atmosphere including oxygen;
placing a plurality of spacers on the first major surface of the first substrate;
placing a solder pre-form over and contacting the coating formed on the first major surface of the first substrate;
bringing together the first and second substrates such that the first major surfaces thereof face one another and form a subassembly;
heating, to a peak temperature of no more than 250 degrees C., the subassembly in order to reflow the solder pre-form and form an edge seal;
following the formation of the edge seal, evacuating a cavity formed between the first and second substrates in making the VIG unit.

26. The method of claim 25 , wherein the solder pre-form comprises either Sn, Ag, and Cu, or In and Ag.

27. The method of claim 25 , wherein the solder pre-form is based on Sn and includes at least one other material selected from the group consisting of post-transition metals or metalloids; Zintl anions from group 13, 14, 15, or 16; and transition metals.

28. The method of claim 25 , wherein the layers comprising nickel each are 10-20 microns thick, and the layer comprising silver is 15-25 microns thick.

29. The method of claim 25 , wherein the layer comprising silicon nitride further comprises oxygen.

30. The method of claim 1 , wherein the layer comprising silicon nitride further comprises oxygen.

Assignees

• Guardian Glass Llc

Inventors

• Veerasamy Vijayen S
• Tucker Patricia
• Bracamonte Martin D

Classifications

• E06B3/6775 Primary

  Evacuating or filling the gap during assembly · CPC title

• E06B3/66357

  Soldered connections or the like · CPC title

• E06B3/67326

  Assembling spacer elements with the panes · CPC title

• C03C27/08

  with the aid of intervening metal · CPC title

• E06B3/6612

  Evacuated glazing units · CPC title