Dielectric adhesive film for electronic paper display device

Patent metadata

Field	Value
Publication number	US-10011743-B2
Application number	US-201214395240-A
Country	US
Kind code	B2
Filing date	May 21, 2012
Priority date	Apr 19, 2012
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

A dielectric adhesive film for an electronic paper display device, by which the operating performance of a flexible display device is excellent even applying a high voltage when the flexible display device is operated, by controlling a dielectric constant with respect to an adhesive film for attaching a lower electrode to which a voltage is applied with an image upper electrode on which particles, which possess electric charges with various colors that change according to an applied voltage, are coated to adjust the electric charges of the adhesive film in the thickness direction to thereby minimize loss of the applied voltage while maintaining an adhesive property and reliability.

First claim

What is claimed is:

1. A dielectric adhesive film for an electronic paper display device,
the dielectric adhesive film being formed to attach to an upper electrode coated with charged particles, and a lower electrode to which voltage can be applied, and having a dielectric constant in a range of 2.0 to 10.0,
wherein the dielectric adhesive film comprises an adhesive layer with a thickness from 4.0 μm to 50.0 μm, and
wherein the adhesive layer has an electrical resistance value in the range of 1.0×10 4 Ω to 9.9×10 9 Ω in the thickness direction of the adhesive layer,
wherein the adhesive layer contains 70 to 95% by weight of an acrylic adhesive to impart adhesive characteristics and reliability, and 10 to 20 parts of a resin per 100 parts of the acrylic adhesive for imparting dielectric characteristics to increase or to compensate for a dielectric constant,
wherein the resin for imparting dielectric characteristics is polyurethane rubber.

2. The film of claim 1 , wherein the adhesive film is formed by laminating a polyester-based high release sheet, the adhesive layer formed on a silicone release coating surface of the high release sheet, and a polyester-based low release sheet formed on the adhesive layer.

3. The film of claim 2 , wherein the adhesive layer contains 0.05 to 5 parts by weight of one or a mixture selected from an epoxy-based cross-linking agent, aziridine-based cross-linking agent or a multi-functional isocyanate-based cross-linking agent, with respect to 100 parts by weight of a base resin produced using an acrylate copolymer.

4. The film of claim 3 , wherein the adhesive layer further contains one or more anti-static agents selected from a carbon nanotube, a conductive organic or inorganic particle, an organic or inorganic salt, and an ionic material, to impart dielectric characteristics.

5. The film of claim 2 , wherein the adhesive layer further contains one or more anti-static agents selected from a carbon nanotube, a conductive organic or inorganic particle, an organic or inorganic salt, and an ionic material, to impart dielectric characteristics.

6. The film of claim 1 , wherein the acrylic adhesive uses, as a base resin, an acrylate copolymer produced by copolymerizing 90 to 99.9% by weight of a monomer that does not have a cross-linkable functional group, and 0.1 to 10% by weight of a monomer having a cross-linkable functional group.

7. The film of claim 6 , wherein the monomer that does not have a cross-linkable functional group is one or a mixture of two or more monomers selected from a group consisting of: methyl(meth)acrylate, ethyl(meth)acrylate, n-propyl(meth)acrylate, n-butyl(meth)acrylate, pentyl(meth)acrylate, hexyl(meth)acrylate, cyclohexyl(meth)acrylate, 2-ethylhexyl(meth)acrylate, isooctyl(meth)acrylate, decyl(meth)acrylate, dodecyl(meth)acrylate, myristyl(meth)acrylate, palmityl(meth)acrylate, stearyl(meth)acrylate, n-tetradecyl(meth)acrylate; an acrylic monomer of acrylonitrile; or a biacrylic monomer containing vinyl acetate or styrene.

8. The film of claim 7 , wherein the adhesive layer further contains one or more anti-static agents selected from a carbon nanotube, a conductive organic or inorganic particle, an organic or inorganic salt, and an ionic material, to impart dielectric characteristics.

9. The film of claim 6 , wherein the monomer having a cross-linkable functional group is one or a mixture of two or more monomers selected from: an acrylic monomer containing any one hydroxy group selected from a group consisting of 2-hydroxy ethyl(meth)acrylate, 2-hydroxy propyl(meth)acrylate, 4-hydroxy butyl(meth) acrylate, 6-hydroxy hexyl(meth)acrylate, 2-hydroxy ethylene glycol(meth)acrylate, and 2-hydroxy propylene glycol(meth)acrylate; an acrylic monomer containing any one carboxyl group selected from a group consisting of (meth)acrylic acid, maleic acid, and fumaric acid; or any one nitrogen-containing acrylic monomer selected from a group consisting of acrylamide, N-vinyl pyrrolidone, and N-vinyl caprolactam.

10. The film of claim 9 , wherein the adhesive layer further contains one or more anti-static agents selected from a carbon nanotube, a conductive organic or inorganic particle, an organic or inorganic salt, and an ionic material, to impart dielectric characteristics.

11. The film of claim 6 , wherein the adhesive layer further contains one or more anti-static agents selected from a carbon nanotube, a conductive organic or inorganic particle, an organic or inorganic salt, and an ionic material, to impart dielectric characteristics.

12. The film of claim 1 , wherein the adhesive layer further contains one or more anti-static agents selected from a carbon nanotube, a conductive organic or inorganic particle, an organic or inorganic salt, and an ionic material, to impart dielectric characteristics.

Assignees

• Kho Dong Han
• Lee Sang Hoon
• Hwang Chang Ik
• Kim Yeon Soo
• Toray Advanced Mat Korea Inc

Inventors

• Kho Dong Han
• Lee Sang Hoon
• Hwang Chang Ik
• Kim Yeon Soo

Classifications

• C09J9/00

  Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks (C09J7/00 takes precedence) · CPC title

• Y10T428/1476

  Release layer · CPC title

• C09J133/08

  Homopolymers or copolymers of acrylic acid esters · CPC title

• C08G18/6229

  Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols · CPC title

• C09J2467/005

  in the release coating · CPC title