Clear paint composition for hot stamping film and painting method using the same

Patent metadata

Field	Value
Publication number	US-10011738-B2
Application number	US-201514963004-A
Country	US
Kind code	B2
Filing date	Dec 8, 2015
Priority date	Oct 5, 2015
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

A clear paint composition for a hot stamping film and a painting method using the same is provided. More particularly, disclosed are a clear paint composition for a hot stamping film which may enhance adhesion by mixing an epoxy-denatured acrylic resin and two light absorber types with an acrylic resin and a polyester polyol resin, may increase weather resistance by simultaneously blocking short and long wavelengths and may enhance chipping resistance, fouling resistance and water resistance by mixing a hardener including reactive silicone therewith, and a painting method using the same.

First claim

What is claimed is:

1. A clear paint composition for a hot stamping film comprising:
a main material part comprising an epoxy-denatured acrylic resin, an acrylic resin, a polyester polyol, a reactive catalyst, a wet additive, a light stabilizer and a solvent; and
a hardener part comprising a hexamethylene diisocyanate trimer-based hardener and a reactive silicone hardener.

2. The clear paint composition according to claim 1 , wherein the main material part comprises 50 to 60% by weight of the epoxy-denatured acrylic resin, 10 to 15% by weight of the acrylic resin, 5 to 10% by weight of polyester polyol, 0.1 to 1.5% by weight of the reactive catalyst, 0.1 to 1% by weight of the wet additive, 1 to 2% by weight of the light stabilizer and 20 to 30% by weight of the solvent.

3. The clear paint composition according to claim 1 , wherein the main material part and the hardener part are mixed in a weight ratio of 2.0:1 to 4.0:1.

4. The clear paint composition according to claim 1 , wherein the epoxy-denatured acrylic resin has an acid value of 3 to 10 mg/KOH, a hydroxyl content of 1 to 5%, and a weight-average molecular weight (Mw) of 8,000 to 20,000.

5. The clear paint composition according to claim 1 , wherein the epoxy-denatured acrylic resin is an epoxy-denatured acrylic resin having a repeated unit structure represented by Formula 1 below:

wherein K, L, M, N and O are relative ratios of each repeated unit thereof and K+L+M+N+O=1; a repeated methyl methacrylate unit K is 0.2 to 0.6; a repeated epoxy acrylate unit L is 0.1 to 0.25; a repeated methyl acrylate unit M is 0.1 to 0.2; a repeated butyl methacrylate unit N is 0.1 to 0.15; and a repeated 2-hydroxyethyl methacrylate unit O is 0.1 to 0.2.

6. The clear paint composition according to claim 1 , wherein the acrylic resin has an acid value of 0.01 to 0.05 mg/KOH, a hydroxyl content of 0.1 to 0.5% and a weight-average molecular weight (Mw) of 9,000 to 15,000.

7. The clear paint composition according to claim 1 , wherein the polyester polyol has a hydroxyl content of 2 to 4% and a weight-average molecular weight (Mw) of 3,000 to 10,000.

8. The clear paint composition according to claim 1 , wherein the reactive catalyst is dibutyl tin dilaurate.

9. The clear paint composition according to claim 1 , wherein the wet additive is a polydimethyl siloxane-based material.

10. The clear paint composition according to claim 1 , wherein the light stabilizer is two or more selected from the group consisting of benzophenones, oxanilides, benzotriazoles, triazines, 4 -benzoyloxy-2,2,6,6-tetramethylpiperidine and 2,4-di-tert-butylphenyl-3,5-di-tert-butyl-benzoate.

11. The clear paint composition according to claim 1 , wherein the solvent is an ester-based material, a hydrocarbon-based material or a mixture thereof.

12. The clear paint composition according to claim 1 , wherein the hardener part comprises 90 to 99% by weight of the hexamethylene diisocyanate trimer-based hardener and 1 to 10% by weight of the reactive silicone hardener.

13. The clear paint composition according to claim 1 , wherein the reactive silicone hardener comprises 0.1 to 1% by weight of an isocyanate group based on a weight of silicone.

14. A method of painting using a clear paint composition for a hot stamping film, the method comprising:
forming a primer layer by spreading, on a painting subject, a primer paint composition comprising an epoxy-denatured acrylic resin, an acrylic resin, a polyester polyol, a reactive catalyst, a wet additive, a light stabilizer and a solvent; and
forming a clear layer by spreading the clear paint composition according to claim 1 on the primer layer.

15. The method according to claim 14 , wherein the primer paint composition comprises 50 to 60% by weight of the epoxy-denatured acrylic resin, 10 to 15% by weight of the acrylic resin, 5 to 10% by weight of polyester polyol, 0.1 to 1.5% by weight of the reactive catalyst, 0.1 to 1% by weight of the wet additive, 1 to 2% by weight of the light stabilizer and 20 to 30% by weight of the solvent.

16. The method according to claim 14 , wherein the painting subject is a polymer film formed through hot stamping.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Cams Co Ltd
• Noroo Bee Chemical Co Ltd
• Cams Co Ltd
• Noroo Bee Chemical Co Ltd

Inventors

• Lee Min Hee
• Lee Seung Mok
• Noh Eun Ju
• Kim Young Seok
• Lee Yong Chul
• Park Kyung Tak

Classifications

• C08F220/281

  and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate · CPC title

• B05D2504/00

  Epoxy polymers · CPC title

• C08G18/4063

  Mixtures of compounds of group C08G18/62 with other macromolecular compounds · CPC title

• B05D7/53

  Base coat plus clear coat type · CPC title

• C08G18/73

  acyclic · CPC title