Process of manufacture of particles with a natural calcium carbonate and ethylene acrylic acid salts base, suspensions and dry pigments obtained, their uses

Patent metadata

Field	Value
Publication number	US-10011732-B2
Application number	US-201615267984-A
Country	US
Kind code	B2
Filing date	Sep 16, 2016
Priority date	Jan 19, 2006
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

The present invention consists of a process of preparation of at least one mineral matter and/or of at least one pigment, including a calcium carbonate made at once partially organophilic and partially hydrophilic, in which the carbonate is blended and/or ground and/or concentrated in an aqueous medium, in the presence of at least one salt of ethylene acrylic acid, one dispersing agent and/or one grinding aid agent, which is introduced before and/or during this treatment stage. Another object of the invention lies in the aqueous dispersions and suspensions of calcium carbonate thus obtained. They may be dried and the dry pigments obtained also constitute an object of the invention. Use of these aqueous dispersions and these dry pigments in the field of plastic, paints and paper constitutes another object of the invention.

First claim

The invention claimed is:

1. An aqueous suspension or dispersion of mineral matter comprising calcium carbonate and at least one salt of ethylene acrylic acid, wherein the carboxylic groupings of the ethylene acrylic acid salt are entirely neutralized or neutralized at a rate of 70 to 99% relative to the total number of the carboxylic sites of the ethylene acrylic acid, with at least one neutralization agent that includes one or more amines, wherein the suspension or dispersion has a dry weight of greater than 65% based on the total weight of the aqueous suspension or dispersion of mineral matter, wherein the ethylene acrylic acid salt has a mass ratio of ethylene monomer to acrylic acid monomer of between 10:90 and 30:70, wherein the ethylene acrylic acid salt has a melt index of between 50 g/10 minutes and 1,500 g/10 minutes when the ethylene acrylic acid salt is totally neutralized, and wherein the ethylene acrylic acid salt has a melt index of between 1,000 g/10 minutes and 1,400 g/10 minutes when the ethylene acrylic acid salt is neutralized at a rate of 70 to 99%.

2. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the salt of the ethylene acrylic acid is present at a dry weight percent of 0.2 to 2% based on the dry weight of mineral matter.

3. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the amine includes one primary amine.

4. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the amine is an alkanolamine.

5. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the amine is 2-amino-2-methyl-1-propanol and/or dimethylethanolamine.

6. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the amine is 2-amino-2-methyl-1-propanol.

7. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the amine is dimethylethanolamine.

8. The aqueous suspension or dispersion of mineral matter according to claim 1 , having a dry weight of greater than 70% based on the total weight of the aqueous suspension or dispersion of mineral matter.

9. The aqueous suspension or dispersion of mineral matter according to claim 1 , having a dry weight of greater than 75% based on the total weight of the aqueous suspension or dispersion of mineral matter.

10. The aqueous suspension or dispersion of mineral matter according to claim 1 , having a dry weight of between 75 and 78% based on the total weight of the aqueous suspension or dispersion of mineral matter.

11. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the mineral matter comprises natural and/or precipitated calcium carbonate.

12. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the mineral matter comprises natural calcium carbonate.

13. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the mineral matter includes, in addition to calcium carbonate, at least one other mineral matter selected from a dolomite, a bentonite, a kaolin, talc, cement, gypsum, lime, magnesia, titanium dioxide, satin white, aluminium trioxide, aluminium trihydroxide, a silica, mica, a talc-calcium carbonate blend, a calcium carbonate-kaolin blend, a blend of calcium carbonate with aluminium trihydroxide or aluminium trioxide, a blend of calcium carbonate with a synthetic or natural fiber, a mineral costructure, a talc-calcium carbonate costructure, or a talc-titanium dioxide costructure, or any blend thereof.

14. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the mineral matter comprises greater than or equal to 70% of calcium carbonate based on the total dry weight of the mineral matter.

15. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the mineral matter has an average diameter of less than 15 μm.

16. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the mineral matter has an average diameter of less than 5 μm.

17. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the mineral matter has an average diameter of between 0.3 and 1.7 μm.

18. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the mineral matter has an average diameter of between 0.9 and 0.9 μm.

19. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein greater than 60% of particles of the mineral matter has a diameter of less than 2 μm.

20. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein greater than 90% of particles of the mineral matter has a diameter of less than 2 μm.

21. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein greater than 99% of particles of the mineral matter has a diameter of less than 2 μm.

22. The aqueous suspension or dispersion of mineral matter according to claim 1 , having a Brookfield viscosity of less than 1,000 mPa·s measured at 100 rpms at 25° C.

23. The aqueous suspension or dispersion of mineral matter according to claim 1 , having a Brookfield viscosity of less than 500 mPa·s measured at 100 rpms at 25° C.

24. The aqueous suspension or dispersion of mineral matter according to claim 1 , having a Brookfield viscosity of between 100 and 300 mPa·s measured at 100 rpms at 25° C.

25. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the salt of ethylene acrylic acid is a salt soluble in an aqueous medium.

26. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the ethylene acrylic acid salt has a melt index of between 200 g/10 minutes and 300 g/10 minutes when the ethylene acrylic acid salt is totally neutralized.

27. The aqueous suspension or dispersion of mineral matter according to claim 1 , which further comprises a dispersing and/or grinding aid agent.

28. The aqueous suspension or dispersion of mineral matter according to claim 1 , wherein the dispersing and/or grinding aid agent is present at a dry weight percent of 0.1 to 2% based on the dry weight of the mineral matter.

29. The aqueous suspension or dispersion of mineral matter according to claim 27 , wherein the dispersing agent and/or grinding aid agent is a homopolymer of acrylic acid and/or a copolymer of acrylic acid with a water-soluble monomer selected from methacrylic acid, maleic acid, itaconic acid, crotonic acid, fumaric acid, isocrotonic acid, aconitic acid, mesaconic acid, sinapic acid, undecylenic acid, angelic acid, canellic acid and/or 2-acrylamido 2-methyl propane sulfonic acid in acid form or partially neutralized, or acrylamide, methylacrylamide, an ester of an acrylic or methacrylic acid, acrylate phosphate, ethylene methacrylate, propylene glycol, vinylpyrrolidone, vinylcaprolactame, vinyl acetate, sodium styrene sulfonate, allylamine, or derivative thereof.

Assignees

• Omya Int Ag

Inventors

• Buri Matthias
• Gane Patrick A C
• Hunziker Philipp
• Burkhalter René
• Karth Beat

Classifications

• C08K3/22

  of metals · CPC title

• C09C1/021

  Calcium carbonates · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• D21H17/69

  modified, e.g. by association with other compositions prior to incorporation in the pulp or paper · CPC title

• C09C1/02 Primary

  Compounds of alkaline earth metals or magnesium {(C09C1/0003, C09C1/0009, C09C1/0015, C09C1/0078 take precedence; dolomitic solids C09C1/009)} · CPC title