Photocurable composition and photocurable inkjet ink containing same, recording method using photocurable composition, and recording method using photocurable inkjet ink

Patent metadata

Field	Value
Publication number	US-10011665-B1
Application number	US-201515127636-A
Country	US
Kind code	B1
Filing date	Mar 19, 2015
Priority date	Mar 31, 2014
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

A photocurable composition containing a photopolymerizable compound and a photoinitiator, wherein the photopolymerizable compound is a radically polymerizable monomer and the photoinitiator is a photoradical initiator. The photocurable composition is characterized by additionally contains a metal chelate compound, wherein the center metal element in the metal chelate compound is selected from metal elements belonging to Group 2, Group 4, Group 8 and Group 13 and the metal chelate compound is contained in an amount of 0.1 to 5% by mass inclusive relative to the whole mass of the photocurable composition. Thus, it becomes possible to provide: a photocurable composition which has sustained adhesiveness and does not undergo shrinking upon curing; and a photocurable inkjet ink.

First claim

The invention claimed is:

1. A photocurable composition comprising:
a photopolymerizable compound; and
a photoinitiator,
wherein:
the photopolymerizable compound is a radical polymerizable monomer,
the photoinitiator is a photoradical initiator,
the photocurable composition contains a metal chelate compound, and
a center metal element of the metal chelate compound is selected from any of group 2, group 4, group 8, and group 13, and the metal chelate compound is contained at 0.1 mass % or more to 5 mass % or less based on a total mass of the photocurable composition, wherein: the metal elements of group 2 are Be, Mg, and Ca,
the metal elements of group 4 are Ti, Zr, and Hf,
the metal elements of group 8 are Fe, Ru, and Os, and
the metal elements of group 13 are B, Al, and Ga.

2. The photocurable composition according to claim 1 , wherein the metal chelate compound is contained in a dissolved state in the photocurable composition.

3. The photocurable composition according to claim 1 ,
wherein:
the photocurable composition contains a crosslinking promoter,
the crosslinking promoter has an active methylene moiety as a partial structure, and
a content of the crosslinking promoter is 5 mass % or more to 30 mass % or less based on the total mass of the photocurable composition.

4. The photocurable composition according to claim 1 ,
wherein:
the photocurable composition contains an organic solvent, and
a content of the organic solvent is 3 mass % or less based on the total mass of the photocurable composition.

5. A photocurable inkjet ink comprising the photocurable composition according to claim 1 .

6. The photocurable inkjet ink according to claim 5 , further comprising a coloring material.

7. The photocurable inkjet ink according to claim 6 ,
wherein:
the coloring material is a pigment, and
the photocurable inkjet ink further contains a pigment dispersant.

8. A recording method using a photocurable composition, the method comprising: imparting the photocurable composition according to claim 1 to a recording medium; and
then curing the photocurable composition by irradiation with actinic radiation.

9. The recording method using a photocurable composition according to claim 8 , wherein the recording medium is any of polypropylene, polyethylene, and polyethylene terephthalate.

10. A recording method using a photocurable inkjet ink in an inkjet recording apparatus including:
an inkjet head that discharges the photocurable inkjet ink according to claim 5 ;
an irradiation part that irradiates the actinic radiation; and
a conveying part that conveys the recording medium, the method comprising: imparting the photocurable inkjet ink to the recording medium with the inkjet head; and
then curing the photocurable inkjet ink by irradiation with actinic radiation by the irradiation part.

11. The recording method using the photocurable inkjet ink according to claim 10 , wherein the recording medium is any of polypropylene, polyethylene, and polyethylene terephthalate.

Assignees

• Konica Minolta Inc

Inventors

• Miyano Masashi
• Toeda Takayuki

Classifications

• C08F222/103

  of trialcohols, e.g. trimethylolpropane tri(meth)acrylate · CPC title

• B41M5/0047

  by ink-jet printing · CPC title

• C08F222/104

  of tetraalcohols, e.g. pentaerythritol tetra(meth)acrylate · CPC title

• C08F222/102

  of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate · CPC title

• C08F216/125

  Monomers containing two or more unsaturated aliphatic radicals, e.g. trimethylolpropane triallyl ether or pentaerythritol triallyl ether · CPC title