Process for production of DME from crude methanol

Patent metadata

Field	Value
Publication number	US-10011548-B2
Application number	US-201314422433-A
Country	US
Kind code	B2
Filing date	Aug 14, 2013
Priority date	Aug 21, 2012
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

The invention provides a process for the production of purified dimethylether (DME). Methanol is dehydrated to provide a first DME-containing product. The first DME-containing product is purified in a two-stage process. The invention also provides an apparatus arranged to carry out said process.

First claim

The invention claimed is:

1. A process for the production of dimethylether (DME), said process comprising:
a. dehydrating a methanol stream in the presence of a catalyst bed in a DME reactor system by passing the methanol stream over the catalyst to provide a first DME-containing product;
b. reducing the first DME-containing product temperature and directly introducing the reduced temperture product into an olefin stripper column, stripping the reduced temperature product in said stripper column into two streams:
i. an olefin stripper light fractions, and
ii. a second DME-containing product;
wherein sensible heat of the reduced temperature product provides energy for the olefin stripper column;

c. introducing the second DME-containing product into a DME column, in which it is separated into:
i. DME column overhead light fractions,
ii. purified DME and
iii. unreacted methanol and water bottoms fractions, and

d. recycling the unreacted methanol and water bottoms fraction of step c.iii. to said DME reactor.

2. The process according to claim 1 , wherein the olefin stripper light fractions is cooled and in a gas/liquid separator, separated in a gas fraction and a reflux liquid and the reflux liquid is used as reflux liquid in the olefin stripper.

3. The process according to claim 1 , wherein one or more of the light fractions are separated into DME-containing off-gases, said off-gases are combined, washed with methanol to extract DME and the DME-containing methanol recycled to the methanol stream inputted to step a.

4. The process according to claim 1 , wherein said methanol stream of step a. is obtained by passing a feed of crude methanol through a combined stabiliser/waste water column.

5. The process according to claim 1 , wherein heat from step a is used to heat the combined stabiliser/waste water column.

Assignees

• Haldor Topsoe As
• Haldor Topsoe As

Inventors

• Dahl Per Juul
• Østergaard Janni

Classifications

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• C07C43/043

  Dimethyl ether · CPC title

• B01J2219/00006

  Large-scale industrial plants · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• C07C41/42 Primary

  by distillation · CPC title