Methods of measuring pH in refinery streams

Patent metadata

Field	Value
Publication number	US-10011542-B2
Application number	US-201615135202-A
Country	US
Kind code	B2
Filing date	Apr 21, 2016
Priority date	Apr 24, 2015
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

At least one pH-sensitive component may contact a refinery stream for measuring the pH of the refinery stream. A light from a light source may be emitted onto the pH-sensitive component, and a detector may detect a first luminescence or color change of chromophore measurement radiated from the pH-sensitive component. A first pH of the refinery stream may be determined from the first luminescence or color change of chromophore measurement.

First claim

What is claimed is:

1. A method for measuring pH in a refinery stream;
wherein the method comprises:
contacting a refinery stream with an apparatus comprising a pH sensitive component deposited as a thin layer or membrane onto or within the apparatus, where the contacting further comprises introducing the pH sensitive component directly into the refinery stream or into a slip stream from the refinery stream;
emitting a light from a light source through the refinery stream onto the pH-sensitive component;
detecting a first luminescence measurement or color change of chromophore measurement radiated from the pH-sensitive component through the refinery stream with a detector; and
determining a first pH of the refinery stream from the first luminescence measurement or the color change of chromophore measurement.

2. The method of claim 1 , wherein the apparatus is present in the refinery stream at a location selected from the group consisting of a dilution steam generator, a distillation tower, a process water stripper, a quench water tower, an oil/water separator, and combinations thereof.

3. The method of claim 1 further comprising altering the pH of the refinery stream when the first pH is outside of a pH range of from about 4.0 to about 9.5.

4. The method of claim 1 , wherein the method occurs in an amount of time that is one minute or less.

5. The method of claim 1 , wherein the light comprises a wavelength ranging from about 200 nm to about 950 nm.

6. The method of claim 1 , wherein the apparatus further comprises a temperature sensor, and wherein the method further comprises detecting a temperature of the refinery stream with the apparatus.

7. The method of claim 1 , wherein the apparatus is selected from the group consisting of a probe, a cuvette, a patch, and combinations thereof.

8. The method of claim 1 , wherein the first luminescence measurement is an absorbance measurement, and wherein the first pH of the refinery stream is determined from the absorbance measurement with the following formula:
pH=pK a +slope×log(Abs sample /Abs pH11 −Abs sample )

where:
pK a is the acid dissociation constant for the refinery stream; pK a =−log 10 K a where K a =([A−][H+])/[HA];
slope is sensitivity of the measurement;
Abs sample is the absorbance measurement of the sample; and
Abs pH11 is the absorbance measurement of the sample at a pH of 11.

9. The method of claim 1 , wherein the refinery stream is selected from the group consisting of an aqueous-based refinery stream, a hydrocarbon-based refinery stream, and combinations thereof.

10. The method of claim 1 , wherein the refinery stream is selected from the group consisting of a quench medium, an effluent stream, a dilution condensate, a dilution steam, a distillation vapor, a mixed C 4 hydrocarbon stream, a light ends hydrocarbon stream, a styrene hydrocarbon stream, cracked gas distillates, hydrotreater feeds, kerosene, a pyrolysis gas stream, and combinations thereof.

11. The method of claim 1 where:
a distance from the light source to the pH sensitive component ranges from about 0.1 to about 100 mm; and
a distance from the detector to the pH sensitive component ranges from about 0.1 to about 100 mm.

12. A method for measuring pH in a refinery stream;
wherein the method comprises:
contacting a refinery stream with a pH probe comprising a pH-sensitive component deposited as a thin layer or membrane onto or within the pH probe, and a light source where the contacting further comprises introducing the pH sensitive component directly into the refinery stream or into a slip stream from the refinery stream;
emitting a light from the light source onto the pH-sensitive component;
detecting a first luminescence measurement radiated from the pH-sensitive component through the refinery stream with a detector; and
determining a first pH of the refinery stream from the first luminescence measurement.

13. The method of claim 12 , wherein the pH probe is attachable to the detector.

14. The method of claim 12 , wherein the pH probe is present in the refinery stream at a location selected from the group consisting of a process stripper, a dilution steam generator, a distillation tower, a quench water tower, an oil/water separator, and combinations thereof.

15. The method of claim 14 , further comprising removing excess refinery fluid from the pH probe after the first luminescence measurement has been detected by a technique selected from the group consisting of vacuuming the pH probe, contacting the pH probe with compressed air, and combinations thereof.

16. The method of claim 15 , further comprising detecting at least a second luminescence measurement from the refinery stream with the pH probe to determine a second pH of the refinery stream from the second luminescence measurement.

17. A method for measuring pH in a refinery stream;
wherein the method comprises:
contacting a refinery stream with a pH patch comprising a pH-sensitive component deposited as a thin layer or membrane onto or within the pH patch, where the contacting further comprises introducing the pH sensitive component directly into the refinery stream or into a slip stream from the refinery stream;
emitting light from a light source through the refinery stream onto the pH-sensitive component; and
detecting a first luminescence measurement radiated from the pH-sensitive component through the refinery stream with a detector;
determining a first pH of the refinery stream from the first luminescence measurement; and
altering the pH of the refinery stream.

18. The method of claim 17 , wherein the refinery stream is selected from the group consisting of a quench medium, an effluent stream, a dilution condensate, a dilution steam, a distillation vapor, a mixed C 4 hydrocarbon stream, a light ends hydrocarbon stream, a styrene hydrocarbon stream, cracked gas distillates, hydrotreater feeds, kerosene, a pyrolysis gas stream, and combinations thereof.

19. The method of claim 17 , wherein the pH patch contacts the refinery stream at a location selected from the group consisting of a dilution steam generator, a distillation tower, a process water stripper, a quench water tower, an oil/water separator, and combinations thereof.

20. The method of claim 17 , wherein the altering the pH of the refinery stream occurs when the first pH is outside of a pH range from about 4.0 to about 9.5.

Assignees

• Baker Hughes Inc
• Baker Hughes A Ge Co Llc

Inventors

• Mo Hua
• Metzler Roger D

Classifications

• G01N21/78

  producing a change of colour · CPC title

• G01N31/221

  for investigating pH value · CPC title

• C10G19/00 Primary

  Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment · CPC title

• G01N21/80

  Indicating pH value · CPC title

• C10G17/00

  Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge · CPC title