Process for obtaining a catalyst composite

Patent metadata

Field	Value
Publication number	US-10011537-B2
Application number	US-201615383502-A
Country	US
Kind code	B2
Filing date	Dec 19, 2016
Priority date	Jan 25, 2008
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

A process for obtaining a catalyst composite comprising the following steps:
a). selecting a molecular sieve having pores of 10- or more-membered rings b). contacting the molecular sieve with a metal silicate different from said molecular sieve comprising at least one alkaline earth metal and one or more of the following metals: Ga, Al, Ce, In, Cs, Sc, Sn, Li, Zn, Co, Mo, Mn, Ni, Fe, Cu, Cr, Ti and V, such that the composite comprises at least 0.1 wt % of silicate.

First claim

The invention claimed is:

1. A process for the catalytic cracking of an olefin-rich feedstock which is selective towards light olefins in the effluent, the process comprising:
contacting a hydrocarbon feedstock containing one or more olefins with a catalyst composite comprising:
at least 10 wt % of a molecular sieve having pores of 10- or more-membered rings;
at least one metal silicate different from said molecular sieve comprising at least one alkaline earth metal, such that the catalyst composite comprises at least 0.1 wt % of silicate, wherein the molecular sieve is a zeolite, wherein the metal silicate is xonotlite (Ca 6 Si 6 Oi 7 (OH) 2 ) to produce an effluent with an olefin content of lower molecular weight than that of the hydrocarbon feedstock.

2. The process according to claim 1 , wherein the catalyst composite comprises metal phosphate.

3. The process according to claim 1 , wherein the catalyst composite comprises matrix material.

4. The process according to claim 1 , wherein the catalyst composite comprises binder.

5. The process of claim 1 comprising:
contacting an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in an XTO reactor with an XTO catalyst composite under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to an XTO reactor effluent comprising olefin products, wherein the XTO catalyst composite comprises:
at least 10 wt % of a molecular sieve having pores of 10- or more-membered rings;
at least one metal silicate, different from said molecular sieve, comprising at least one alkaline earth metal, such that the XTO catalyst composite comprises at least 0.1 wt % of silicate,

wherein the XTO reactor effluent comprises light olefins and a heavy hydrocarbon fraction and is sent to a fractionation section to separate the light olefins from the heavy hydrocarbon fraction;
wherein the hydrocarbon fraction is the hydrocarbon feedstock containing the one or more olefins to be contacted with the catalyst composite.

6. The process according to claim 5 , wherein the olefin products are fractionated to form a stream comprising essentially ethylene and at least a part of said stream is recycled in the XTO reactor to increase-propylene production.

7. The process according to claim 5 , wherein the contacting a hydrocarbon feedstock containing one or more olefins with a catalyst composite is performed in an OCP reactor; and
an OCP reactor effluent from the OCP reactor is sent to a fractionator and the light olefins are recovered; wherein hydrocarbons having 4 carbon atoms or more are recycled at an inlet of the OCP reactor, optionally mixed with heavy hydrocarbon recovered from the XTO reactor effluent.

8. The process according to claim 7 , wherein the OCP reactor comprises a fixed bed reactor, a moving bed reactor, or a fluidized bed reactor.

9. The process according to claim 7 , wherein, before recycling the hydrocarbons having 4 carbon atoms or more at the inlet of the OCP reactor, said hydrocarbons having 4 carbon atoms or more are sent to a second fractionator to purge the heavies.

10. The process according to claim 7 , wherein, in order to adjust a propylene to ethylene ratio of the process, ethylene in whole or in part is recycled over the OCP reactor; wherein said ethylene is from a fractionation section of the XTO reactor, from a fractionation section of the OCP reactor, from both the fractionation section of the XTO reactor and the fractionation section of the OCP reactor, or from an optional common recovery section.

11. The process according to claim 7 , wherein, in order to adjust propylene to ethylene ratio of the process, ethylene in whole or in part is recycled over the XTO reactor; wherein said ethylene is from a fractionation section of the XTO reactor, from a fractionation section of the OCP reactor, from both the fractionation section of the XTO reactor and the fractionation section of the OCP reactor, or—from an optional common recovery section.

12. The process according to claim 5 , wherein the XTO reactor effluent comprise ethylene, and wherein the ethylene is polymerized optionally with one or more comonomers.

13. The process according to claim 5 , wherein the XTO reactor effluent comprise propylene, and wherein the propylene is polymerized optionally with one or more comonomers.

14. The process according to claim 5 , wherein more than 50% by weight of olefins having 4 or more carbon atoms within the XTO reactor effluent are butenes.

15. The process according to claim 5 , wherein more than 80% by weight of hydrocarbons having 4 or more carbon atoms within the XTO reactor effluent are C 4 to C 8 olefins.

16. The process according to claim 1 , wherein the zeolite is selected from the group consisting of MFI, MOR, MEL, clinoptilolite, FER, FAU, MWW, BETA, ZSM-21, ZSM-22, ZSM-23, ZSM-42, ZSM-57, LTL, and combinations thereof.

17. The process according to claim 1 , wherein the molecular sieve is a ZSM-5 zeolite.

Assignees

• Total Res & Technology Feluy

Inventors

• Nesterenko Nikolai
• Vermeiren Walter
• Van Donk Sander

Classifications

• B01J27/16

  containing oxygen {, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr} · CPC title

• B01J2229/186

  not in framework positions · CPC title

• B01J29/7007

  Zeolite Beta · CPC title

• C08F10/06

  Propene · CPC title

• B01J2229/42

  Addition of matrix or binder particles · CPC title