CO2 recovery device and method for cleaning filtration membrane device of CO2 recovery device

Patent metadata

Field	Value
Publication number	US-10010828-B2
Application number	US-201514893342-A
Country	US
Kind code	B2
Filing date	Feb 2, 2015
Priority date	Feb 5, 2014
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

A filtration membrane device which uses a filter to collect solid contents remaining in a branched lean solution cleans the filter by using a low-concentration CO 2 absorption liquid circulating within the system as cleaning water (containing the absorption liquid); rough cleaning, which returns the low-concentration CO 2 absorption liquid used for cleaning to a lean solution supply line, is performed; the filter is finish-cleaned by cleaning water from outside the system which does not include the CO 2 absorption liquid; the CO 2 absorption liquid which is adhered to the solid contents is washed and removed; finish-cleaning water which includes the CO 2 absorption liquid is returned to the lean solution supply line the moisture content within the system is maintained at a prescribed value by adjusting the water balance in an absorption tower and the concentration of the CO 2 absorption liquid which circulates within the system is kept at a prescribed concentration.

First claim

The invention claimed is:

1. A CO 2 recovery system comprising:
an absorption tower which brings an exhaust gas containing CO 2 into contact with a CO 2 absorption liquid to remove CO 2 ;
an absorption liquid regeneration tower which regenerates a rich solution, which has absorbed CO 2 , through heat exchange;
a rich solution supply line through which the rich solution is extracted from the absorption tower and is introduced into the absorption liquid regeneration tower;
a lean solution supply line through which a lean solution from which CO 2 regenerated in the absorption liquid regeneration tower has been emitted is extracted from the absorption liquid regeneration tower, and is introduced into the absorption tower, and the lean solution is reused as the CO 2 absorption liquid in the absorption tower; and
a filtration membrane device which is interposed in a lean-solution branch line branched from the lean solution supply line, a rich solution branch line branched from the rich solution supply line, or both the solution branch lines, and collects solid contents remaining in a branched solution using a filter, and returns filtrate, which has passed through the filter, to the lean solution supply line, the rich solution supply line or both the solution supply lines;
wherein the filtration membrane device in which the filter has been used to collect the solid contents is configured to rough-clean the filter by using cleaning water containing CO 2 absorption liquid circulating within a system; return rough-cleaning water to the lean solution supply line, the rich solution supply line or both the solution supply lines; finish-clean the filter by using cleaning water which does not include the CO 2 absorption liquid and which is from outside the system to wash out and remove the CO 2 absorption liquid which is adhered to the collected solid contents; return finish-cleaning water which includes the CO 2 absorption liquid to the lean solution supply line, the rich solution supply line or both the solution supply lines; maintain a moisture content in the system at a prescribed value by adjusting a water balance in the absorption tower; and keep a concentration of the CO 2 absorption liquid which circulates within the system at a prescribed concentration.

2. The CO 2 recovery system according to claim 1 ,
wherein the absorption tower is configured to adjust the water balance therein by controlling the temperature of cleaning water in a cleaning section.

3. The CO 2 recovery system according to claim 1 ,
wherein the absorption tower is configured to adjust the water balance therein by controlling the temperature of cooling water in a cooling tower which cools the exhaust gas containing CO 2 before being introduced into the absorption tower.

4. The CO 2 recovery system according to claim 1 ,
wherein the absorption liquid regeneration tower includes:
a separation drum which condenses steam in emission gas containing CO 2 gas that has entrained the steam discharged from a top of the absorption liquid regeneration tower, and separates condensed water,
wherein the absorption tower includes:
a CO 2 recovery section which brings the exhaust gas containing CO 2 into contact with the CO 2 absorption liquid to absorb CO 2 in the exhaust gas;
at least one or more cleaning sections which are disposed on a downstream side of the CO 2 recovery section with respect to an exhaust gas flow, cool CO 2 -removed exhaust gas from which CO 2 has been removed, and recover an entrained CO 2 absorption liquid using the cleaning water; and
a condensed water receiving section which is disposed on a bottom side of each of the cleaning sections, and recovers condensed water within the cleaning section, and
wherein the system is configured to supply any one or both of the condensed water recovered in the condensed water receiving section of the absorption tower and the condensed water separated in the separation drum as the cleaning water containing the CO 2 absorption liquid circulating within the system for the rough cleaning.

5. The CO 2 recovery system according to claim 1 ,
wherein the filtration membrane device is configured to remove the solid contents collected by the filter by performing reverse washing using gas or a cleaning liquid supplied from the outside of the system.

6. The CO 2 recovery system according to claim 1 ,
wherein at least two systems of the filters are provided in parallel in the lean solution branch line, the rich solution branch line or the both the solution branch lines, and alternately collect the solid contents in the branched solution.

7. The CO 2 recovery system according to claim 1 ,
wherein the CO 2 absorption liquid is an amine-based absorption liquid.

8. A method for cleaning a filtration membrane device of a CO 2 recovery system, comprising:
bringing an exhaust gas containing CO 2 into contact with a CO 2 absorption liquid to remove CO 2 in an absorption tower;
regenerating a rich solution, which has absorbed CO 2 , through heat exchange in an absorption liquid regeneration tower;
introducing the rich solution extracted from the absorption tower into the absorption liquid regeneration tower through a rich solution supply line;
extracting a lean solution from which CO 2 regenerated in the absorption liquid regeneration tower has been emitted from the absorption liquid regeneration tower to be introduced into the absorption tower through a lean solution supply line, and reusing the lean solution as the CO 2 absorption liquid in the absorption tower; and
collecting solid contents remaining in a branched solution in a lean solution branch line, a rich solution branch line, or both the branch lines using a filter, and returning filtrate, which has passed through the filter, to the lean solution supply line, the rich solution supply line or both the solution supply lines,
wherein, the filter is rough-cleaned by cleaning water containing the CO 2 absorption liquid circulating within the system; rough-cleaning water is returned to the lean solution supply line, the rich solution supply line or both the solution supply lines; the filter is finish-cleaned by cleaning water which does not include the CO 2 absorption liquid and which is from outside the system to wash out and remove the CO 2 absorption liquid which is adhered to the collected solid contents; finish-cleaning water which includes the CO 2 absorption liquid is returned to the lean solution supply line, the rich solution supply line or both the solution supply lines; a moisture content in the system is maintained at a prescribed value by adjusting a water balance in the absorption tower; and a concentration of the CO 2 absorption liquid which circulates within the system is kept at a prescribed concentration.

9. The method for cleaning the filtration membrane device of the CO 2 recovery system according to claim 8 ,
wherein any one or both of condensed water recovered in a condensed water receiving section of the absorption tower and condensed water separated in a separation drum are used as the cleaning water containing the CO 2 absorption liquid circulating within the system for the rough cleaning.

10. The method for cleaning the filtration membrane device of the CO 2 recovery system according to claim 8 ,
wherein the CO 2 absorption liquid is an amine-based absorption liquid.

11. The method for cleaning the filtration membrane device of the CO 2 recovery system according to claim 8 ,
wherein the water balance in the absorption tower is adjusted by controlling the temperature of cleaning water in a cleaning section.

12. The method for cleaning the fi

Assignees

• Mitsubishi Heavy Ind Ltd

Inventors

• Hirata Takuya
• Nagayasu Hiromitsu
• Tanaka Hiroshi
• Noborisato Tomoki
• Oishi Tsuyoshi

Classifications

• B01D53/1425 Primary

  Regeneration of liquid absorbents · CPC title

• B01D53/1475

  Removing carbon dioxide · CPC title

• B01D61/147

  Microfiltration · CPC title

• B01D65/02

  Membrane cleaning or sterilisation {; Membrane regeneration} · CPC title

• B01D2258/0283

  Flue gases · CPC title