Method for manufacturing shaped product with maintained isotrophy

Patent metadata

Field	Value
Publication number	US-10006677-B2
Application number	US-201414530018-A
Country	US
Kind code	B2
Filing date	Oct 31, 2014
Priority date	May 31, 2011
Publication date	Jun 26, 2018
Grant date	Jun 26, 2018

Abstract

The present invention provides a method for manufacturing a shaped product constituted by a fiber-reinforced composite material including reinforcing fibers and a thermoplastic resin. The shaped product maintains isotropy of the fibers to the end thereof even if press-molded under conditions in which charge ratio of a prepreg to a die is low. Specifically, the method includes using a specific prepreg obtained by impregnating the reinforcing fibers with thermoplastic resin, and molding-processing the prepreg under specific conditions.

First claim

What is claimed is:

1. A prepreg comprising:
reinforcing fibers having an average fiber length of 5 mm to 100 mm; and
a thermoplastic resin,
wherein the reinforcing fibers are substantially two-dimensionally randomly oriented at a fiber areal weight of 25 g/m 2 to 10000 g/m 2 ,
reinforcing fiber bundles (A) constituted by the reinforcing fibers of a critical single fiber number or more, the critical single fiber number being defined by equation (1), are included in an amount of 20 Vol % or more and less than 99 Vol % with respect to the total amount of the reinforcing fibers in the prepreg,
an average number of the reinforcing fibers (N) in the reinforcing fiber bundles (A) satisfies equation (2):
Critical single fiber number=600 /D   (1)

0.7×10 4 /D 2 <N< 1×10 5 /D 2   (2)

wherein, in equation (1) and equation (2), D represents an average fiber diameter (μm) of single reinforcing fibers,
wherein the reinforcing fiber bundles (A) are classified with thickness units per about 0.2 mm; and
a void fraction of the prepreg is 0% to 30%.

2. The prepreg according to claim 1 ,
wherein a content of the thermoplastic resin in the prepreg is 50 parts to 1000 parts by mass with respect to 100 parts by mass of the reinforcing fibers.

3. The prepreg according to claim 1 ,
wherein a thickness of the prepreg is 0.1 mm or more and 30 mm or less.

4. The prepreg according to claim 1 ,
wherein the reinforcing fibers are at least one of selected from the group consisting of a carbon fiber, an aramid fiber, and a glass fiber.

5. A shaped product comprising a fiber-reinforced composite material, which is obtained by a method for manufacturing, the method comprising:
arranging the prepreg according to claim 1 set at a temperature of the melting point or more and less than the thermal decomposition temperature in the case where the thermoplastic resin is crystalline or at a temperature of the glass transition temperature or more and less than the thermal decomposition temperature in the case where the thermoplastic resin is amorphous in a mold to be a charge ratio represented by equation (3) is 50% or more and 100% or less, the mold which is controlled to a temperature less than the melting point temperature in the case where the thermoplastic resin is crystalline or a temperature less than the glass transition temperature in the case where the thermoplastic resin is amorphous:
charge ratio (%)=100×[base material area (mm 2 )/mold cavity projection area (mm 2 )]  (3)

wherein, in equation (3), a base material area represents a projection area of all the arranged prepreg in a draft direction, and
a mold cavity projection area represents a projection area in the draft direction; and
obtaining the shaped product by completion of molding the prepreg at a temperature less than the melting point in the case where the thermoplastic resin is crystalline or at a temperature less than the glass transition temperature in the case where the thermoplastic resin is amorphous, while pressurizing the prepreg within the mold,
wherein a ratio (Eδ) obtained by dividing a larger tensile modulus by a smaller tensile modulus among tensile modulus in an arbitrary direction and a direction perpendicular thereto is 1.0 to 1.3.

6. The shaped product according to claim 5 ,
wherein a thickness variation of the shaped product satisfies a range of an average value in thickness ±10%.

Assignees

• Teijin Ltd

Inventors

• Taniguchi Michiharu
• Arakawa Motoomi
• Nagakura Yasunori
• Arai Tsukasa
• Obata Akihiko

Classifications

• Y10T428/24479

  including variation in thickness · CPC title

• Y10T428/24994

  Fiber embedded in or on the surface of a polymeric matrix · CPC title

• F25B49/02

  for compression type machines, plants or systems · CPC title

• B29C70/305

  Spray-up of reinforcing fibres with or without matrix to form a non-coherent mat in or on a mould (B29C41/365, B29C70/32, B29C70/34, B29C70/502, B29C70/508 take precedence; coating a former by spraying plastics B29C41/08) · CPC title

• B29K2077/00

  Use of {PA, i.e.} polyamides, e.g. polyesteramides {or derivatives thereof}, as moulding material · CPC title