Polymer plugs for well control

Patent metadata

Field	Value
Publication number	US-10006265-B2
Application number	US-201514861330-A
Country	US
Kind code	B2
Filing date	Sep 22, 2015
Priority date	Sep 22, 2015
Publication date	Jun 26, 2018
Grant date	Jun 26, 2018

Abstract

Systems, apparatus, and methods for controlling a well blowout comprising: a flow control device such as a blowout preventer on a wellbore; a control fluid aperture fluidly connected with the wellbore for introducing a control fluid and/or a plug-forming agent such as a polymer, monomer, resinous, and/or crosslinkable material, through a control fluid aperture and into the primary throughbore while wellbore blowout fluid flows through the wellbore; and optionally, a weighted fluid aperture positioned in the wellbore conduit below the control fluid aperture for introducing a weighted fluid or another fluid or plug-forming agent into the wellbore.

First claim

The invention claimed is:

1. A method of performing a wellbore intervention operation to reduce an uncontrolled flow of wellbore blowout fluid from a subterranean wellbore, the method comprising:
providing a flow control device, the flow control device engaged proximate a top end of a wellbore conduit that includes a wellbore throughbore, the flow control device including a primary throughbore coaxially aligned with and comprising a portion of the wellbore throughbore;
providing a control fluid aperture proximate the top end of the wellbore conduit, the control fluid aperture being fluidly connected with the primary throughbore;
providing a plug-forming agent aperture in the wellbore throughbore at an upstream location in the wellbore throughbore with respect to the control fluid aperture and with respect to the direction of wellbore blowout fluid flow through the wellbore throughbore;
providing a weighted fluid aperture in the wellbore throughbore at an upstream location in the wellbore throughbore with respect to the control fluid aperture and with respect to the direction of wellbore blowout fluid flow through the wellbore throughbore;
introducing a control fluid through the control fluid aperture and into the wellbore throughbore so as to reduce a wellbore blowout fluid flow rate through the wellbore throughbore by at least 25% as compared to a wellbore blowout fluid flow rate prior to introduction of the control fluid into the throughbore;
introducing a plug-forming agent through the plug-forming agent aperture and into the wellbore throughbore while the wellbore blowout fluid flows from the subterranean formation through the wellbore throughbore at the reduced wellbore blowout fluid flow rate, whereby the plug-forming agent comprises at least one of a polymerizable monomer and a polymer;
at least one of polymerizing and crosslinking the plug-forming agent within the wellbore throughbore to create an impediment to further reduce flow of the wellbore blowout fluid through the wellbore throughbore; and
introducing a weighted fluid through the weighted fluid aperture and into the wellbore throughbore subsequent to introducing the control fluid through the control fluid aperture and subsequent to introducing the plug-forming agent through the plug-forming agent aperture.

2. The method of claim 1 , further comprising introducing the weighted fluid through the weighted fluid aperture and into the wellbore throughbore while introducing the control fluid through the control fluid aperture.

3. The method of claim 1 , further comprising introducing the weighted fluid through the weighted fluid aperture and into the wellbore throughbore after the wellbore blowout fluid has stopped flowing through the wellbore throughbore.

4. The method of claim 1 , whereby the control fluid further comprises water.

5. The method of claim 4 , whereby the control fluid comprises seawater.

6. The method of claim 1 , further comprising creating the plug-forming agent within the wellbore throughbore by polymerization of the monomer or polymer within the wellbore throughbore.

7. The method of claim 4 , further comprising providing a polymerization catalyst into the wellbore throughbore to mix with the monomer or polymer within the wellbore throughbore.

8. The method of claim 1 , further comprising creating the plug-forming agent within the wellbore throughbore by crosslinking a polymer while the polymer is positioned within the wellbore throughbore.

9. The method of claim 1 , wherein the plug-forming agent adheres to metal surfaces within the wellbore throughbore.

10. The method of claim 1 , further comprising mixing water and the plug-forming agent within the wellbore throughbore to activate crosslinking or polymerization of the plug-forming agent.

11. The method of claim 1 , wherein the plug-forming agent comprises a dicyclopentadiene (DCPD).

12. The method of claim 11 , further comprising using a Grubbs' Ru-based ring opening metathesis catalyst to crosslink the dicyclopentadiene (DCPD).

13. The method of claim 1 , wherein the plug-forming agent comprises a siloxane.

14. The method of claim 13 , wherein the siloxane comprises alkoxy groups.

15. The method of claim 14 , wherein the alkoxy groups comprise at least one of methoxy groups and ethoxy groups.

16. The method of claim 13 , wherein the siloxane crosslinks in the presence of water.

17. The method of claim 13 , wherein the crosslinking comprises polymerization.

18. The method of claim 13 , wherein the crosslinking comprises chemical bonding of polymer chains.

19. The method of claim 13 , further comprising crosslinking the siloxane in the presence of water using thermal energy from the blowout fluid.

20. The method of claim 13 , selecting a catalyst for crosslinking the siloxane using thermal energy from the blowout fluid, such that the siloxane crosslinks at a temperature above a threshold crosslinking temperature.

21. The method of claim 20 , further comprising selecting a crosslinking temperature of at least 50 degrees C.

22. The method of claim 1 , further comprising heating at least a portion of the control fluid prior to introducing the control fluid into the wellbore throughbore.

23. The method of claim 22 , further comprising introducing a heated fluid into the wellbore throughbore while introducing the control fluid into the wellbore throughbore.

24. The method of claim 13 , further comprising introducing siloxane and water into the wellbore throughbore using separate lines and separate ports.

25. The method of claim 1 , comprising introducing the control fluid into the wellbore throughbore at a control fluid introduction rate that is at least 25% of the wellbore blowout fluid flow rate from the wellbore throughbore prior to introducing the control fluid into the wellbore throughbore.

26. The method of claim 1 , further comprising prior to introducing the plug-forming agent into the wellbore, introducing into the wellbore throughbore at least one of a surfactant and a solvent to remove at least one of hydrocarbon wax, paraffin, tar, and hydrocarbon-based coatings from metal surfaces within the wellbore throughbore to enable a product of the plug-forming agent to adhere to the metal surfaces within the wellbore throughbore.

27. The method of claim 1 , comprising providing the control fluid aperture in at least one of a blowout preventer and a drilling spool.

28. The method of claim 1 , comprising providing the control fluid aperture in or upstream of the well control device and providing the weighted fluid aperture in another wellbore component upstream from the well control device with respect to the direction of flow of wellbore blowout fluid flowing from the formation and through the wellbore throughbore.

29. The method of claim 1 , further comprising prior to introducing the control fluid into the wellbore throughbore, introducing a preliminary control fluid into the primary throughbore at a control fluid introduction rate of at least 50% of the wellbore blowout fluid flow rate prior to introduction of the control fluid into the wellbore throughbore.

30. The method of claim 29 , further comprising introducing the preliminary control fluid into the primary throughbore at a control fluid introduction rate of at least 100% of a wellbore blowout fluid flow rate prior to introduction

Assignees

• Nedwed Timothy J
• Brant Patrick
• Exxonmobil Upstream Res Co

Inventors

• Nedwed Timothy J
• Brant Patrick

Classifications

• E21B33/068

  having provision for introducing objects or fluids into, or removing objects from, wells (cementing-heads E21B33/05) · CPC title

• E21B33/035 Primary

  specially adapted for underwater installations (E21B33/043, E21B33/064, E21B33/076 take precedence) · CPC title

• E21B33/064 Primary

  specially adapted for underwater well heads · CPC title

• E21B33/134

  Bridging plugs · CPC title

• E21B33/13 Primary

  Methods or devices for cementing, for plugging holes, crevices or the like · CPC title