Polypropylene compound with improved optical property and gel level

Patent metadata

Field	Value
Publication number	US-10005898-B2
Application number	US-201515539964-A
Country	US
Kind code	B2
Filing date	Dec 28, 2015
Priority date	Dec 30, 2014
Publication date	Jun 26, 2018
Grant date	Jun 26, 2018

Abstract

Composition for producing films with low amount of gels and good haze, wherein said composition comprises a polypropylene and a high density polyethylene powder.

First claim

The invention claimed is:

1. A composition comprising
(a) at least 85 parts per weight (ppw) based on 100 ppw of the composition of a polypropylene (PP), and
(b) greater than 0 but not more than 15 parts per weight (ppw) based on 100 ppw of the composition of a high density polyethylene (HDPE),
wherein said high density polyethylene (HDPE) has particle top cut d90 of below 1000 μm.

2. The composition according to claim 1 , wherein the composition is obtained by mixing said polypropylene (PP) with said high density polyethylene (HDPE).

3. The composition according to claim 1 , wherein the high density polyethylene (HDPE) has a median particle size d50 of below 800 μm.

4. The composition according to claim 1 , wherein the high density polyethylene (HDPE) has
(a) a melting temperature (Tm) in the range of 120 to 150° C.;

and/or
(b) a melt flow rate MFR2 (190° C., 2.16 kg) in the range of 10 to 30 g/10 min;

and/or
(c) a density of at least 930 kg/m3.

5. The composition according to claim 1 , wherein the polypropylene (PP) is a random propylene copolymer having a comonomer content in the range of 0.5 to 6.0 mol-%.

6. The composition according to claim 1 , wherein the polypropylene (PP) has
(a) a melt flow rate MFR2 (230° C.) measured according to ISO 1133 from 5 to 15 g/10 min;

and/or
(b) a xylene cold soluble (XCS) fraction in the range of 1.0 to 6.0 wt.-%.

7. The composition according to claim 1 being free of slip agent(s).

8. A film made from the composition according to claim 1 .

9. The film according to claim 8 , wherein said film has
(a) haze of below 5.0% measured on a 50 μm cast film according to ASTM D1003-00;

and/or
(b) a gel index of less than 30.

10. The film according to claim 8 , wherein the film is a cast film or blown film.

11. A process for producing a composition wherein
(a) at least 85 parts per weight (ppw) based on 100 ppw of the composition of a polypropylene (PP), and
(b) greater than 0 but not more than 15 parts per weight (ppw) based on 100 ppw of the composition of a high density polyethylene (HDPE),

are mixed,
wherein said high density polyethylene (HDPE) has particle top cut d90 of below 1000 μm.

12. The process according to claim 11 , wherein the high density polyethylene (HDPE) has a median particle size d50 of below 800 μm.

13. The for producing a film by feeding a composition according to claim 1 to a cast film line or blown film line and subsequently obtaining a film.

14. The according to claim 11 , wherein (a) and (b) are dry- or melt-mixed.

15. The for lowering the gel index of a film, comprising producing a film from a composition comprising a high density polyethylene (HDPE) having a particle top cut d90 of below 1000 μm and a polypropylene.

16. The according to claim 15 , wherein the gel index of a film produced using the composition comprising the high density polyethylene (HDPE) and the polypropylene is lower compared to the gel index of a film (film 2) made under the same conditions using the same composition except that the high density polyethylene (HDPE) is replaced by the same amount by weight of the polypropylene.

17. The according to claim 15 , wherein
(a) the high density polyethylene (HDPE) has a median particle size d50 of below 800 μm;

and/or
(b) the propylene is a polypropylene (PP) is a random propylene copolymer having a comonomer content in the range of 0.5 to 6.0 mol %;

and/or
(c) the composition is free of slip agent(s).

18. The according to claim 15 , wherein the composition comprises
(a) at least 85 parts per weight (ppw) based on 100 ppw of the composition of a polypropylene (PP), and
(b) greater than 0 but not more than 15 parts per weight (ppw) based on 100 ppw of the composition of a high density polyethylene (HDPE),
wherein said high density polyethylene (HDPE) has particle top cut d90 of below 1000 μm.

19. The film according to claim 10 , wherein said film is metallized.

Assignees

• Abu Dhabi Polymers Co Ltd Borouge
• Borealis Ag
• Abu Dhabi Polymers Co Ltd Borouge

Inventors

• Van Houcke Daniel
• Dixit Niraj
• Singh Raghvendra

Classifications

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• C08J2323/14

  Copolymers of propene (C08J2323/16 takes precedence) · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• B05D7/16

  using synthetic lacquers or varnishes · CPC title

• C08L2203/16

  used for films · CPC title