Treatment of alcohol compositions

Patent metadata

Field	Value
Publication number	US-10005707-B2
Application number	US-201415107674-A
Country	US
Kind code	B2
Filing date	Dec 19, 2014
Priority date	Dec 24, 2013
Publication date	Jun 26, 2018
Grant date	Jun 26, 2018

Abstract

Process for reducing the water and carboxylic acid content of an alcohol composition containing at least one C 1-4 alcohol, water and at least one C 1-4 carboxylic acid by (a) forming a vapor phase alcohol composition A and a liquid phase alcohol composition B, (b) separating a second vapor phase alcohol composition C and an aqueous phase D from the liquid phase alcohol composition B, the aqueous phase D containing the majority of the carboxylic acid that was present in the liquid phase alcohol composition B; (c) passing the vapor phase alcohol composition A to a drying unit, (d) passing the vapor phase alcohol composition C to a drying unit; and (e) recovering an alcohol composition from the drying units of steps (c) and (d). The recovered alcohol composition of step (e) has a reduced water and carboxylic acid content.

First claim

The invention claimed is:

1. A process for reducing the water and carboxylic acid content of an alcohol composition comprising at least one alcohol having from one to four carbon atoms, water and at least one carboxylic acid having from one to four carbon atoms, wherein said process comprises:
(a) forming a vapour phase alcohol composition A and a liquid phase alcohol composition B from the alcohol composition;
(b) separating a second vapour phase alcohol composition C and an aqueous phase D from the liquid phase alcohol composition B in a distillation column, wherein the aqueous phase D contains the majority of the carboxylic acid that was present in the liquid phase alcohol composition B;
(c) passing the vapour phase alcohol composition A to a drying unit comprising a desiccant;
(d) passing the vapour phase alcohol composition C to a drying unit comprising a desiccant; and
(e) recovering an alcohol composition from the drying unit of step (c) and the drying unit of step (d);
wherein the recovered alcohol composition of step (e) has a reduced water and carboxylic acid content.

2. A process as claimed in claim 1 , wherein the vapour phase alcohol composition A and the liquid phase alcohol composition B are formed by vaporisation of the alcohol composition.

3. A process as claimed in claim 1 , wherein the vapour phase alcohol composition A and liquid phase alcohol composition B are formed by pre-dividing the alcohol composition into a first portion and a second portion, passing the first portion to a vaporisation unit so that substantially all of the first portion is vaporised in the vaporisation unit to form the vapour phase alcohol composition A, and passing the second portion to the distillation column as the liquid phase alcohol composition B.

4. A process as claimed in claim 1 , wherein the vapour phase alcohol composition A and liquid phase alcohol composition B are formed by pre-dividing the alcohol composition into a first portion and a second portion, passing the first portion to a vaporisation unit so that the first portion is divided in the vaporisation unit into the vapour phase alcohol composition A and a third portion, and passing the second portion and the third portion to the distillation column as the liquid phase alcohol composition B.

5. A process as claimed in claim 1 , wherein the vaporisation step does not result in a significant difference in the concentration of water present in the vapour phase alcohol composition A and the liquid phase alcohol composition B.

6. A process as claimed in claim 1 , wherein the vapour phase alcohol composition A and the vapour phase alcohol composition C are passed to the same drying unit comprising a desiccant.

7. A process as claimed in claim 6 , wherein the vapour phase alcohol composition A and the vapour phase alcohol composition C are combined prior to being passed to the drying unit comprising a desiccant.

8. A process as claimed in claim 1 , wherein the alcohol composition comprises ethanol.

9. A process as claimed in claim 1 , wherein the alcohol composition comprises acetic acid.

10. A process as claimed in claim 1 , wherein the alcohol composition comprises at least one butanol.

11. A process as claimed in claim 1 , wherein the alcohol composition comprises butyric acid.

12. A process as claimed in claim 1 , wherein the alcohol composition has a water concentration in the range of from 0.05 wt % to 10 wt %.

13. A process as claimed in claim 1 , wherein the alcohol composition has a carboxylic acid concentration in the range of 500 ppmw to 5 wt %.

14. A process as claimed in claim 1 , further comprising using a portion of the alcohol composition having a reduced water and carboxylic acid content recovered in step (e) to regenerate the drying unit of step (c) and/or step (d), and optionally passing a portion of the resulting stream comprising alcohol and water to the distillation column.

15. A method of preparing a fuel alcohol composition from an alcohol composition comprising at least one alcohol having from one to four carbon atoms, water and at least one carboxylic acid having from one to four carbon atoms, wherein said method involves:
(a) determining the concentration of water and carboxylic acid present in the alcohol composition;
(b) if the alcohol composition comprises a concentration of water which is greater than the azeotropic concentration for the alcohol composition, passing the entire alcohol composition to a distillation column of step (c) as a liquid phase alcohol composition B;
if the alcohol composition comprises a concentration of water which is equal to or lower than the azeotropic concentration for the alcohol composition, and the carboxylic acid concentration is equal to or lower than the maximum desired concentration of carboxylic acid in the fuel alcohol composition, vaporising the entire alcohol composition to form a vapour phase alcohol composition A; or
if the alcohol composition comprises a concentration of water which is equal to or lower than the azeotropic concentration for the alcohol composition, and the carboxylic acid concentration is greater than the maximum desired concentration of carboxylic acid in the fuel alcohol composition, forming a vapour phase alcohol composition A and a liquid phase alcohol composition B from the alcohol composition;
(c) separating a second vapour phase ethanol composition C and an aqueous phase D from the liquid phase ethanol composition B, if present, in a distillation column, wherein the aqueous phase D contains the majority of the carboxylic acid that was present in the liquid phase alcohol composition B;
(d) passing the vapour phase alcohol composition A, if present, to a drying unit comprising a desiccant;
(e) passing the vapour phase alcohol composition C, if present, to a drying unit comprising a desiccant; and
(f) recovering a fuel alcohol composition from the drying unit of step (d), if present, and the drying unit of step (e), if present;
wherein the recovered fuel alcohol composition has a reduced water content.

Assignees

• Bp Plc

Inventors

• Bough Matthew

Classifications

• B01D3/002

  by continuous methods · CPC title

• C07C37/76

  by steam distillation · CPC title

• C10L2200/0469

  Renewables or materials of biological origin · CPC title

• C10L2290/12

  Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel · CPC title

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title