Article having coating including compound of aluminum, boron and nitrogen

Patent metadata

Field	Value
Publication number	US-10005696-B2
Application number	US-201415022572-A
Country	US
Kind code	B2
Filing date	Aug 25, 2014
Priority date	Sep 18, 2013
Publication date	Jun 26, 2018
Grant date	Jun 26, 2018

Abstract

An article includes a substrate and a coating on the substrate. The coating includes a compound of aluminum, boron and nitrogen in a continuous chemically bonded network having Al—N bonds and B—N bonds. Also disclosed is an article wherein the substrate is a plurality of fibers and the coating is a conformed coating of a compound of aluminum, boron and nitrogen having Al—N bonds and B—N bonds. The fibers are disposed in a matrix. Also disclosed is a method of protecting an article from environmental conditions. The method includes protecting a substrate that is susceptible to environmental chemical degradation using a coating that includes a compound of aluminum, boron and nitrogen having Al—N bonds and B—N bonds.

First claim

What is claimed is:

1. An article comprising:
a plurality of fibers having a conformed coating thereon, the conformed coating including a compound of aluminum (Al), boron (B) and nitrogen (N) including Al—N bonds and B—N bonds, wherein the compound includes an atom of nitrogen covalently bonded to an atom of boron and an atom of aluminum, and the compound has a composition B x Al (1−x) N, where x is 0.001 to 0.999; and
a matrix in which the plurality of fibers is disposed.

2. The article as recited in claim 1 , wherein the Al—N bonds and the B—N bonds are molecularly distributed in a continuous chemically bonded network that has a nanodispersion of domains of the Al—N bonds and the B—N bonds.

3. The article as recited in claim 1 , wherein the conformed coating has a uniform thickness and consists of the compound of aluminum (Al), boron (B) and nitrogen (N).

4. The article as recited in claim 1 , wherein, by weight percentage, the conformed coating includes a greater amount of aluminum (Al) than boron (B).

5. The article as recited in claim 1 , wherein the conformal coating includes an amount of B—N, by weight, of no greater than 50%.

6. The article as recited in claim 1 , wherein the compound is a continuous chemically bonded network including the Al—N bonds and the B—N bonds.

7. The article as recited in claim 1 , wherein the plurality of fibers are selected from the group consisting of silicon-containing fibers, carbon fibers and combinations thereof.

8. The article as recited in claim 7 , wherein the plurality of fibers are silicon carbide fibers.

9. The article as recited in claim 1 , wherein the conformed coating contacts peripheral surfaces of central cores of the fibers.

10. The article as recited in claim 1 , wherein the matrix is a silicon-containing material.

11. The article as recited in claim 1 , wherein the compound includes a carbon atom covalently bonded to a silicon atom.

12. The article as recited in claim 1 , wherein the compound includes a carbon atom covalently bonded to a nitrogen atom.

13. The article as recited in claim 1 , wherein the compound includes a carbon atom bonded to a nitrogen atom and a silicon atom.

14. The article as recited in claim 1 , wherein the conformal coating includes an amount of B—N, by weight, of no greater than 10%.

15. The article as recited in claim 14 , wherein the compound includes a carbon atom bonded to a nitrogen atom and a silicon atom.

16. The article as recited in claim 1 , wherein the conformal coating has a chemical structure selected from the group consisting of:

17. A method of protecting an article from environmental conditions, the method comprising:
protecting a substrate that is susceptible to environmental chemical degradation using a coating on the substrate, the coating including a compound of aluminum (Al), boron (B) and nitrogen (N) having Al—N bonds and B—N bonds, the compound includes an atom of nitrogen covalently bonded to atoms of boron and aluminum, and the compound has a composition B x Al (1−x) N, where x is 0.001 to 0.999.

18. The method as recited in claim 17 , wherein the coating includes an amount of B—N, by weight, of no greater than 50%.

Assignees

• United Technologies Corp

Inventors

• Schmidt Wayde R

Classifications

• C04B35/584

  based on silicon nitride · CPC title

• C04B41/5063

  Aluminium nitride · CPC title

• D06M11/58

  with nitrogen or compounds thereof, e.g. with nitrides (with ammonium halides D06M11/13) · CPC title

• F05D2300/2282

  of boron · CPC title

• C04B35/62868 Primary

  Boron nitride · CPC title