Porous inorganic/organic homogenous copolymeric hybrid materials for chromatographic separations and process for the preparation thereof
US-9211524-B2 · Dec 15, 2015 · US
US10005256B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10005256-B2 |
| Application number | US-201213523141-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 14, 2012 |
| Priority date | Jun 14, 2012 |
| Publication date | Jun 26, 2018 |
| Grant date | Jun 26, 2018 |
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A film for a composite article may include a non-weakened portion and a weakened portion. The weakened portion may have at least one property that may be lower than the property of the non-weakened portion.
Opening claim text (preview).
What is claimed is: 1. A non-fibrous film for a composite article, comprising: a plurality of non-fibrous non-weakened portions extending along the length of the non-fibrous film; a plurality of non-fibrous weakened portions having one of the following three arrangements: (a) at least one of the non-fibrous weakened portions having a tortuous shape and being non-intersected by any transverse weakened segments along the length of the non-fibrous film; (b) at least one of the non-fibrous non-weakened portions having a tortuous shape and being non-interrupted by any transverse weakened segments along the length of the non-fibrous film; (c) some of the non-fibrous weakened portions being intersected by transverse weakened segments and at least one of the non-fibrous weakened portions being non-intersected by transverse weakened segments extending from opposite sides of the weakened portion at the same location thereon along the length of the non-fibrous film, the weakened portions being continuously straight along the length of the non-fibrous film; wherein each transverse weakened segment is non-parallel to the weakened portions; and the weakened portions having at least one property that has a value that is lower than the value of the property of the plurality of non-weakened portions. 2. The film of claim 1 , wherein: the property comprises at least one of a tensile strength, a tensile modulus, and an ultimate strain. 3. The film of claim 1 , wherein: the non-fibrous film comprises a stretched film having a stretched direction oriented generally parallel to a lengthwise direction of the weakened portions. 4. The film of claim 1 , wherein: the non-fibrous film comprises a corrugated film having a corrugated cross-sectional shape. 5. The film of claim 1 , wherein: the non-fibrous film has a film thickness in a range of from approximately 3 microns to 5000 microns. 6. The film of claim 1 , wherein: at least one of the non-weakened portions has an elongated cross-sectional shape with an aspect ratio of a non-weakened portion width to a film thickness of approximately 3 to approximately 500. 7. The film of claim 1 , wherein the film is formed from at least one of: a thermoplastic material, a thermosetting material, and a metallic material. 8. The film of claim 7 , wherein: the non-fibrous film comprises a stretched film formed of thermoplastic material. 9. The film of claim 8 , wherein: the stretched film is one of unidirectionally stretched and bidirectionally stretched. 10. The film of claim 1 , further comprising: an adhesive layer located between at least one pair of the non-fibrous films. 11. A composite article, comprising: a plurality of non-fibrous films arranged in a stacked formation; at least one of the non-fibrous films having a plurality of non-weakened portions extending along the length of the non-fibrous film; a plurality of non-fibrous weakened portions having one of the following three arrangements: (a) at least one of the non-fibrous weakened portions having a tortuous shape and being non-intersected by any transverse weakened segments along the length of the at least one non-fibrous film; (b) at least one of the non-fibrous non-weakened portions having a tortuous shape and being non-interrupted by any transverse weakened segments along the length of the non-fibrous film; (c) some of the non-fibrous weakened portions being intersected by transverse weakened segments and at least one of the non-fibrous weakened portions being non-intersected by transverse weakened segments extending from opposite sides of the weakened portion at the same location thereon along the length of the at least one non-fibrous film, the weakened portions being continuously straight along the length of the non-fibrous film; wherein each transverse weakened segment is non-parallel to the weakened portions; and the weakened portions having at least one property that has a value that is lower than the value of the property of the plurality of non-weakened portions. 12. The composite article of claim 11 , further comprising: an adhesive layer located between at least one pair of the plurality of non-fibrous films. 13. The composite article of claim 11 , wherein: the property comprises a property including at least one of a tensile strength, a tensile modulus, and an ultimate strain. 14. The composite article of claim 11 , wherein: at least one of the plurality of non-fibrous films comprises a stretched film having a stretched direction oriented generally parallel to a lengthwise direction of the weakened portion. 15. The composite article of claim 14 , wherein: the stretched film is one of unidirectionally stretched and bidirectionally stretched. 16. The composite article of claim 11 , wherein: the plurality of non-fibrous films comprise corrugated films arranged in the stacked formation. 17. The composite article of claim 16 , further comprising: a pair of face sheets mounted on opposite sides of the stacked formation of the corrugated films. 18. A method of forming a film, comprising the steps of: forming a non-fibrous film having a plurality of non-fibrous non-weakened portions extending along the length of the non-fibrous film, and a plurality of non-fibrous weakened portions having one of the following three arrangements: (a) at least one of the non-fibrous weakened portions having a tortuous shape and being non-intersected by any transverse weakened segments along the length of the non-fibrous film; (b) at least one of the non-fibrous non-weakened portions having a tortuous shape and being non-interrupted by any transverse weakened segments along the length of the non-fibrous film; (c) some of the non-fibrous weakened portions being intersected by transverse weakened segments and at least one of the non-fibrous weakened portions being non-intersected by transverse weakened segments extending from opposite sides of the weakened portion at the same location thereon along the length of the non-fibrous film, the weakened portions being continuously straight along the length of the non-fibrous film; wherein each transverse weakened segment is non-parallel to the weakened portions; and configuring the non-fibrous film such that the weakened portions have at least one property having a value that is lower than the value of the property of the non-weakened portions. 19. The method of claim 18 , wherein: the property comprises at least one of a tensile strength, a tensile modulus, and an ultimate strain. 20. The method of claim 18 , further comprising the step of: forming the tortuous shape as lengthwise weakened segments that are offset from one another and which are interconnected by transverse weakened segments. 21. The method of claim 18 , further comprising the step of: providing the non-fibrous film as a stretched film. 22. A method of forming a composite article, comprising the steps of: providing a plurality of non-fibrous films, at least one of the films having a plurality of non-fibrous non-weakened portions extending along the length of the at least one non-fibrous film, and a plurality of non-fibrous weakened having one of the following three arrangements: (a) at least one of the non-fibrous weakened portions having a tortuous shape and being non-intersected by any transverse weakened segments along the length of the non-fibrous film; (b) at least one of the non-fibrous non-weakened portions having a tortuous
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