Phosphoric acid fuel cell component having a polymer impregnated region

Patent metadata

Field	Value
Publication number	US-10003091-B2
Application number	US-201314766994-A
Country	US
Kind code	B2
Filing date	Feb 19, 2013
Priority date	Feb 19, 2013
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

According to an example embodiment, a method of making a phosphoric acid fuel cell component includes situating at least one polymer film layer against a permeable component layer. The polymer film layer comprises a polymer that is chemically resistant to phosphoric acid. The polymer film layer is melted. The permeable component layer is impregnated with the melted polymer to thereby establish a region on the component layer that is impermeable to phosphoric acid. The impregnated region also provides a seal against reactant leakage from the component.

First claim

We claim:

1. A method of making a phosphoric acid fuel cell component, comprising the steps of:
situating at least one polymer film layer comprising a polymer that is chemically resistant to phosphoric acid against a permeable component layer;
melting the polymer film layer;
applying a first pressure to the polymer and component layer until a temperature of at least the polymer reaches a melting temperature of the polymer; and
applying a second, greater pressure to the polymer and component layer while increasing a temperature of at least the polymer to a second temperature above the melting temperature of the polymer; and
impregnating the permeable component layer with the melted polymer to thereby establish a region on the component layer that is impermeable to phosphoric acid.

2. The method of claim 1 , comprising situating the polymer film along at least a portion of a perimeter of the component layer.

3. The method of claim 1 , comprising
using a plurality of polymer film layers that includes at least one polymer film layer that is thicker than at least one other of the polymer film layers; and
situating the thicker one of the polymer film layers between the component layer and the at least one other of the polymer film layers.

4. The method of claim 1 , comprising
placing the polymer film layer and the permeable component layer within a press;
situating the polymer film layer between the press and the permeable component layer; and
situating a release film between the polymer film layer and the press.

5. The method of claim 4 , comprising providing a vent through the release film for allowing gas to escape from between the release film and the other layers.

6. The method of claim 1 , wherein the second temperature is approximately 20° C. higher than the melting temperature of the polymer.

7. The method of claim 1 , wherein the polymer film layer comprises a high melt flow polymer that is non-wetting and thermally stable below a temperature of approximately 220° C.

8. The method of claim 1 , wherein
the polymer film layer comprises a frame that has a geometry corresponding to a perimeter of the component layer; and
the polymer film layer has a surface area that is less than a surface area of the component layer.

9. The method of claim 1 , wherein the polymer film layer has a thickness corresponding to at least a porosity of the substrate multiplied by a thickness of the substrate.

10. The method of claim 1 , wherein the component layer comprises at least one of an electrode, a gas diffusion layer and a catalyst layer.

11. The method of claim 1 , comprising situating a first polymer film layer against one side of the component layer and a second polymer film layer against an oppositely facing side of the component layer.

12. A phosphoric acid fuel cell component made by the process comprising the steps of:
situating at least one polymer film layer comprising a polymer that is chemically resistant to phosphoric acid against a permeable component layer;
melting the polymer film layer;
applying a first pressure to the polymer and component layer until a temperature of at least the polymer reaches a melting temperature of the polymer; and
applying a second, greater pressure to the polymer and component layer while increasing a temperature of at least the polymer to a second temperature above the melting temperature of the polymer; and
impregnating the permeable component layer with the melted polymer to thereby establish a region on the component layer that is impermeable to phosphoric acid.

13. The phosphoric acid fuel cell component of claim 12 , wherein the process comprises
using a plurality of polymer film layers that includes at least one polymer film layer that is thicker than at least one other of the polymer film layers; and
situating the thicker one of the polymer film layers between the component layer and the at least one of the other polymer film layers.

14. The phosphoric acid fuel cell component of claim 12 , wherein the process comprises
placing the polymer film layer and the permeable component layer within a press;
situating the polymer film layer between the press and the permeable component layer;
situating a release film between the polymer film layer and the press; and
providing a vent through the release film for allowing gas to escape from between the release film and the other layers.

Assignees

• Doosan Fuel Cell America Inc

Inventors

• Osepowicz Nicholas Edward
• Khandelwal Manish

Classifications

• H01M8/0286

  Processes for forming seals · CPC title

• H01M8/0234

  Carbonaceous material · CPC title

• H01M8/023

  Porous and characterised by the material · CPC title

• H01M8/086

  Phosphoric acid fuel cells [PAFC] · CPC title

• H01M4/86

  Inert electrodes with catalytic activity, e.g. for fuel cells · CPC title