Ion conductive inks and solutions for additive manufacturing of lithium microbatteries

Patent metadata

Field	Value
Publication number	US-10003059-B2
Application number	US-201514882127-A
Country	US
Kind code	B2
Filing date	Oct 13, 2015
Priority date	Oct 13, 2015
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

A separator made of ion conductive ink is produced by additive manufacturing. A micro-battery is produced with the separator made of ion conductive ink located between the battery's anode and cathode. The separator functions to keep the anode and cathode apart and to facilitate the transport of ions to produce an operative micro-battery.

First claim

The invention claimed is:

1. A method of making a micro-battery, comprising the steps of:
creating a three dimensional model of a micro-battery separator, wherein said three dimensional model of a micro-battery separator has sides, a top, and a bottom, and comprises anode micro-channels extending from said top to said sides and cathode micro-channels extended from said bottom to said sides;
using said three dimensional model of a micro-battery separator to produce a micro-battery separator by additive manufacturing, wherein said additive manufacturing uses ion conductive ink to produce said micro-battery separator, and wherein said micro-battery separator has sides, a top, and a bottom, and comprises anode micro-channels extending from said top to said sides and cathode micro-channels extended from said bottom to said sides;
creating a seal for the micro-battery by adding a material that seals said sides of said micro-battery separator leaving said top and said bottom unsealed;
positioning a top electrical conductive plate on said top of said micro-battery separator;
adding a top electrode connected to said top electrical conductive plate;
positioning a bottom electrical conductive plate on said bottom of said micro-battery separator;
adding a bottom electrode connected to said bottom electrical conductive plate;
filling said anode micro-channels in said micro-battery separator with anode material;
filling said cathode micro-channels in said micro-battery separator with cathode material; and
adding an outer casing.

2. The method of making a micro-battery of claim 1 , wherein said additive manufacturing is projection micro-stereolithography.

3. The method of making a micro-battery of claim 1 , wherein said additive manufacturing is 3D printing.

4. The method of making a micro-battery of claim 1 , wherein said ion conductive ink is Lithium Bis(trifluoromethane)sulfonimide, LiTFSI) and tetraglyme solvent.

5. The method of making a micro-battery of claim 1 , wherein said ion conductive ink is methacrylpropylsulfate (MPS) salts and PEGDA.

6. The method of making a micro-battery of claim 1 , wherein said ion conductive ink is methacrylpropylsulfate salts and PEGDA/PEGMA having a

chemical structure.

7. The method of making a micro-battery of claim 1 , wherein said micro-battery separator has a matrix of anode micro-channels and a matrix of cathode micro-channels wherein said matrix of anode micro-channels and said matrix of cathode micro-channels do not interconnect and form self-contained matrices for said anode material in said anode micro-channels and said cathode material in said cathode micro-channels.

8. The method of making a micro-battery of claim 7 , wherein said matrix of anode micro-channels and said matrix of cathode micro-channels are interwoven to provide an interpenetrating network.

Assignees

• L Livermore Nat Security Llc

Inventors

• Duoss Eric B
• Campbell Patrick G
• Floyd Iii William C
• Jackson Julie A
• Merrill Matthew
• Sharpe Conner T
• Spadaccini Christopher M
• Stadermann Michael
• Zhu Cheng

Classifications

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C09D11/00

  Inks · CPC title

• C09D11/52

  Electrically conductive inks · CPC title

• H01M6/40

  Printed batteries {, e.g. thin film batteries} · CPC title

• H01M10/0436 Primary

  Small-sized flat cells or batteries for portable equipment · CPC title