Organic light emitting diode and organic light emitting display device including the same

Patent metadata

Field	Value
Publication number	US-10003040-B2
Application number	US-201514731729-A
Country	US
Kind code	B2
Filing date	Jun 5, 2015
Priority date	Aug 21, 2014
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

An organic light emitting element, includes a first electrode and a second electrode facing each other; an emission layer between the first electrode and the second electrode; and an electron injection layer between the second electrode and the emission layer, the electron injection layer including an oxide having a relative dielectric constant of 10 or more and a metal having a work function of 4.0 eV or less.

First claim

What is claimed is:

1. An organic light emitting element, comprising:
a first electrode and a second electrode facing each other;
an emission layer between the first electrode and the second electrode; and
an electron injection layer between the second electrode and the emission layer,
the electron injection layer including an oxide having a relative dielectric constant of 10 or more and a metal having a work function of 4.0 eV or less,
wherein the metal having a work function of 4.0 eV or less includes Ce, Sm, Eu, Gd, La, Nd, Tb, Lu, or an alloy thereof, and
wherein the oxide having a relative dielectric constant of 10 or more includes one or more of Yb 2 O 3 , Sm 2 O 3 , Nb 2 O 3 , Gd 2 O 3 , or Eu 2 O 3 .

2. The organic light emitting element as claimed in claim 1 , wherein the oxide having a relative dielectric constant of 10 or more and the metal having a work function of 4.0 eV or less form a single layer.

3. The organic light emitting element as claimed in claim 1 , further comprising an electron transport layer between the emission layer and the electron injection layer and a hole transport layer between the emission layer and the first electrode,
wherein the hole transport layer and the electron transport layer each includes an organic material.

4. The organic light emitting element as claimed in claim 1 , wherein the electron injection layer is formed of a plurality of layers, and each of the plurality of layers includes at least one of the oxide having a relative dielectric constant of 10 or more and the metal having a work function of 4.0 eV or less.

5. The organic light emitting element as claimed in claim 4 , wherein the electron injection layer includes:
a first layer including the oxide having a relative dielectric constant of 10 or more, and
a second layer on the first layer and including the metal having a work function of 4.0 eV or less.

6. The organic light emitting element as claimed in claim 4 , wherein the electron injection layer includes:
a first layer including the metal having a work function of 4.0 eV or less, and
a second layer on the first layer and including the oxide having a relative dielectric constant of 10 or more.

7. An organic light emitting display, comprising:
a substrate;
a gate line on the substrate;
a data line and a driving voltage line;
a switching thin film transistor connected to the gate line and the data line;
a driving thin film transistor connected to the switching thin film transistor and the driving voltage line; and
an organic light emitting element connected to the driving thin film transistor, wherein the organic light emitting element includes:
a first electrode and a second electrode facing each other;
an emission layer between the first electrode and the second electrode; and
an electron injection layer between the second electrode and the emission layer,
the electron injection layer including an oxide having a relative dielectric constant of 10 or more and a metal having a work function of 4.0 eV or less,
wherein the metal having a work function of 4.0 eV or less includes Ce, Sm, Eu, Gd, La, Nd, Tb, Lu, or an alloy thereof, and
wherein the oxide having a relative dielectric constant of 10 or more includes one or more of Yb 2 O 3 , Sm 2 O 3 , Nb 2 O 3 , Gd 2 O 3 or Eu 2 O 3 .

8. The organic light emitting display as claimed in claim 7 , further comprising an electron transport layer between the emission layer and the electron injection layer and a hole transport layer between the emission layer and the first electrode,
wherein the hole transport layer and the electron transport layer each includes an organic material.

9. The organic light emitting display as claimed in claim 8 , wherein the electron injection layer is formed of a plurality of layers, and each of the plurality of layers includes at least one of the oxide having a relative dielectric constant of 10 or more and the metal having a work function of 4.0 eV or less.

10. The organic light emitting display as claimed in claim 9 , wherein the electron injection layer includes:
a first layer including the oxide having a relative dielectric constant of 10 or more, and
a second layer on the first layer and including the metal having a work function of 4.0 eV or less.

11. The organic light emitting display as claimed in claim 9 , wherein the electron injection layer includes:
a first layer including the metal having a work function of 4.0 eV or less, and
a second layer on the first layer and including the oxide having a relative dielectric constant of 10 or more.

12. The organic light emitting display as claimed in claim 7 , wherein the emission layer includes a red emission layer, a green emission layer, and a blue emission layer, and further includes an auxiliary layer under the blue emission layer.

13. The organic light emitting display as claimed in claim 12 , further comprising a red resonance auxiliary layer disposed below the red light emission layer and a green resonance auxiliary layer disposed below the green light emission layer.

14. The organic light emitting display as claimed in claim 12 , wherein the auxiliary layer includes a compound represented by Chemical Formula 1:

wherein, in Chemical Formula 1, A1, A2, and A3 are each hydrogen, carbazole, dibenzothiophene, dibenzofuran (DBF), or biphenyl, and a, b, and c are each an integer of zero to four.

15. The organic light emitting display as claimed in claim 12 , wherein the auxiliary layer includes a compound represented by Chemical Formula 2:

wherein, in Chemical Formula 2, a is 0 to 3, b and c are each 0 to 3, X is selected from O, N, or S, and each X is the same as or different from each other.

Assignees

• Samsung Display Co Ltd

Inventors

• Kim Dong Chan
• Kim Won Jong
• Kim Eung Do
• Seo Dong Kyu
• Lee Jong Hyuk
• Yim Sang Hoon
• Chu Chang Woong

Classifications

• H05B33/14

  characterised by the chemical or physical composition or the arrangement of the electroluminescent material {, or by the simultaneous addition of the electroluminescent material in or onto the light source} · CPC title

• C07D471/04

  Ortho-condensed systems · CPC title

• C07D307/78

  Benzo [b] furans; Hydrogenated benzo [b] furans · CPC title

• H01L51/5092 Primary

  Electricity · mapped topic

• H01L2251/303

  Electricity · mapped topic