Adaptive heat flow calorimeter

Patent metadata

Field	Value
Publication number	US-10001417-B2
Application number	US-201715490281-A
Country	US
Kind code	B2
Filing date	Apr 18, 2017
Priority date	Aug 11, 2014
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

Apparatus and methods are provided for providing flexible and repairable testing capabilities for systems that generate or absorb heat such as energy storage systems. One embodiment can include a temperature bath structure adapted to contain and maintain a fluid bath at a predetermined temperature, an outer containment structure adapted to insert into the temperature bath structure, heat sinks, thermal sensor assemblies, and an internal containment structure where the thermal sensor assemblies and heat sinks removably attach to different sections of the inner containment structure so as to measure heat flow into or out of the inner containment structure's different sections. Embodiments of the invention enable rapid insertion/removal of samples as well as replacement of sections of the system including embodiments or parts of thermal sensor assemblies as well as enabling separate thermal measurements associated with different sections of a sample under test within the inner containment structure.

First claim

The invention claimed is:

1. A method of using a thermal energy testing system comprising:
providing a sample for testing;
providing an inner containment structure of a calorimeter comprising a plurality of wall sections including side sections, a selectively removal top section, and a bottom section, wherein said inner containment structure further comprises attaching a plurality of thermal isolation barriers disposed between each of said sections to thermally isolate each section from all adjacent sections as well as additional thermal isolation barriers disposed on outer surfaces of said inner containment structure;
inserting a sample into said inner containment structure;
removably coupling said top section of said inner containment structure to respective side sections of adjacent walls of said inner containment structure;
providing a plurality of thermal sensor assemblies and respectively coupling each of said thermal sensor assemblies to said outer surfaces of said inner containment structure so said sensor assemblies can be removed and replaced, wherein said sensor assemblies are physically separated from adjacent edges of other sensors in proximity to each other so as to prevent thermal energy from transferring between said sensor assemblies by direct physical contact with each other;
removably attaching ones of a plurality of heat sink to respective said outer surfaces of said inner containment structure;
inserting inner containment structure with said sample into an outer containment structure;
coupling said top section of inner containment structure to said outer containment structure;
inserting said outer containment structure into a fluid bath;
allowing said sample to discharge; and
measuring and recording a heat flow data through each side of said inner containment structure independently of other sides of said inner containment structure.

2. The method of claim 1 wherein said sample comprises an electrical energy structure that is charged or discharged at a controlled rate or said sample comprises other materials such as propellants or pyrotechnics that decompose upon heating.

3. The method of claim 1 further comprising a heat flow generated by the stimulated charge, stimulated discharge, or self-discharge of said sample applying a charge to said sample to generate a heat flow.

4. The method of claim 1 wherein said sample is charged at a constant charge rate.

5. The method of claim 1 wherein the measuring and recording step further comprises:
sending said heat flow data to a data acquisition device;
sending said data from said data acquisition device to a processing system; and
importing said data to an input output device.

6. The method of claim 5 wherein said data is sent through a plurality of wires wherein said plurality of wires terminates in a common plug.

7. The method of claim 1 further comprising measuring the heat capacity of said sample.

8. The method of claim 7 wherein measuring the heat capacity of said sample further comprises increasing said temperature of said calibration bath; and
measuring the amount of energy absorbed into the test chamber to raise said sample to a new temperature that is in equilibrium with said calibration bath.

9. The method of claim 1 wherein said attaching steps associated with said inner containment structure and said thermal sensors are repeated for each said outer surface of said inner containment structure.

10. A method of manufacture comprising:
providing an outer containment structure;
providing an inner containment structure comprising a plurality of sections comprising side sections, a top section, and a bottom section, said inner containment structure further comprises thermal isolation barriers adapted to thermally isolate each side section from each other;
positioning each one of a plurality of thermal sensor assemblies respectively in contact with an outer surface of each of said plurality of inner containment structure so as to separately determine heat measurements with respect to each said sections, wherein said thermal sensors comprise at least one thermopile, wherein each thermal sensor assembly has a separate signal output from all other thermal sensor assemblies;
removably attaching each one of a plurality of heat sinks respectively to each one of said plurality of thermal sensor assemblies and each section of said sections by inserting at least one of a plurality of non-heat conducting fasteners through each one of said heat sinks, each one of said plurality of thermal sensor assemblies into separate sections of said inner containment structure, wherein said heat sink is also in contact with said outer containment structure;
placing said inner containment structure into said outer containment structure; and
coupling each of said signal outputs of said plurality of thermal sensor assemblies' signal outputs with a signal processing system comprising a section operable to receive signals from said separate thermal sensor assemblies and determine said heat measurements.

11. The method of claim 10 further comprising inserting a sample having materials which generate or consume heat in said inner containment structure.

12. The method of claim 11 further comprising attaching a plurality of cables through an aperture in said inner containment structure from said sample to a charging system.

13. The method of claim 10 further comprising placing said outer containment structure in a calibration bath structure with a thermal conductive fluid inside said calibration bath structure.

14. The method of claim 10 where said attaching step further comprises using a non-heat conductive bolt to attach said thermal sensor assemblies respectively to said inner containment structure sections.

15. The method of claim 10 where the attachment steps are repeated for each said outer surface of said inner containment structure.

16. The method of claim 10 wherein said thermal sensor assembly comprises:
a first heat sink wall section;
a plurality of thermopiles coupled to said first heat sink wall section; and
a second heat sink wall section coupled to said plurality of thermopiles wherein said first heat sink wall section and said second heat wall section have said plurality of thermopiles disposed there between.

17. The method of claim 16 wherein each wall, top, and bottom of said inner containment structure comprises a separate said thermal sensor assembly.

18. The method of claim 16 wherein said thermal sensor assembly further comprises a first heat sink wall section and second heat sink wall section disposed on opposing sides of said thermal sensor assembly, wherein said method further comprises providing a non-thermally conductive fastener to couple said first heat sink wall section and said second heat sink wall section with said thermal sensor assembly a respective inner containment structure section.

19. The method of claim 16 further comprising:
attaching a plurality of wires to said plurality of thermopiles;
connecting said plurality of wires to a data acquisition system;
connecting said data acquisition system to a processing system; and
connecting said processing system to an input output device.

20. A method of repairing a thermal testing system comprising:
providing a calorimetric measuring unit;
providing an inner containment structure comprising a plurality of sections comprising side sections, a top section, and a bottom section, said inner containment structure further comprises thermal isolation barr

Assignees

• Us Navy
• Us Navy

Inventors

• Ubelhor Ryan
• Ellison Daniel
• Pierce Cecilia

Classifications

• G01K19/00 Primary

  Testing or calibrating calorimeters · CPC title

• G01K17/00

  Measuring quantity of heat (measuring temperature by calorimetry G01K3/00 - G01K11/00; specially adapted for measuring thermal properties of materials, e.g. specific heat, heat of combustion G01N) · CPC title

• G01N25/20

  by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity (calorimeters per se G01K) · CPC title