Aqueous low friction coating for telecommunication cables

Patent metadata

Field	Value
Publication number	US-10000716-B2
Application number	US-201315039894-A
Country	US
Kind code	B2
Filing date	Dec 4, 2013
Priority date	Dec 4, 2013
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

A fluoropolymer coating composition comprises: fluorinated homopolymer particles dispersed in water, fluorinated copolymer particles dispersed in water, non-fluorinated polymer particles dispersed in water; and at least one aziridine compound comprising at least two aziridine groups. The composition is especially useful in low friction coating for telecommunication cables.

First claim

What is claimed is:

1. A fluoropolymer coating composition comprising:
fluorinated homopolymer particles dispersed in water,
fluorinated copolymer particles dispersed in water, wherein the fluorinated copolymer particles comprise a copolymer of tetrafluoroethylene, hexafluoropropylene and vinylidene fluoride,
non-fluorinated polymer particles dispersed in water; and
at least one aziridine compound comprising at least two aziridine groups,

wherein the fluoropolymer coating comprises 3 wt. % to about 35 wt. %, non-fluorinated polymer, 15 wt. % to 75 wt. % fluorinated homopolymer and 10 wt. % to 75 wt. % fluorinated copolymer after drying.

2. The fluoropolymer coating composition of claim 1 wherein the non-fluorinated polymer particles comprise a polyurethane latex material.

3. The fluoropolymer coating composition of claim 1 wherein the non-fluorinated polymer particles comprise an acrylic latex material.

4. The fluoropolymer coating composition of claim 1 wherein the fluorinated homopolymer particles comprise polytetrafluoroethylene.

5. The fluoropolymer coating composition of claim 1 further comprising inorganic oxide nanoparticles.

6. The fluoropolymer coating composition of claim 5 wherein the inorganic oxide nanoparticles comprise nanoparticle silica having an average particle size of less than 100 nm.

7. An article having a low friction surface, comprising:
a substrate having an exposed polymer surface and a thin layer of a low friction coating disposed on the exposed polymer surface of the substrate, wherein the low friction coating comprises a fluorinated homopolymer, a fluorinated copolymer wherein the fluorinated copolymer particles comprise a copolymer of tetrafluoroethylene, hexafluoropropylene and vinylidene fluoride, and non-fluorinated polymer; that have been crosslinked by a polyazidine crosslinking agent, wherein the fluoropolymer coating comprises 3 wt. % to about 35 wt. %, non-fluorinated polymer, 15 wt. % to 75 wt. % fluorinated homopolymer and 10 wt. % to 75 wt. % fluorinated copolymer after drying.

8. The article of claim 7 , wherein the exposed polymer surface comprises a low surface energy plastic.

9. The article of claim 7 , wherein the exposed polymer surface can be selected from polyethylene, polyester, and polyvinyl chloride.

10. The article of claim 7 , wherein the non-fluorinated polymer comprises at least one of a polyurethane and an acrylic polymer.

11. The article of claim 7 , wherein the fluorinated homopolymer is polytetrafluoroethylene.

12. The article of claim 7 , further comprising inorganic oxide nanoparticles.

13. The article of claim 7 , wherein the substrate is a film substrate.

14. The article of claim 7 , wherein the article is a low friction telecommunication cable comprising at least one optical fiber surrounded by a polymeric cable jacket wherein the low friction coating is applied to the external surface polymeric cable jacket.

15. The article of claim 14 , wherein the low friction coating has a coating thickness that is less than 100 microns.

16. The article of claim 14 , wherein telecommunication cable can be characterized by a minimum critical dimension and wherein the ratio of the coating thickness to the minimum critical dimension of the telecommunication cable is 6:94.

17. The article of claim 14 , wherein the coefficient of friction of an uncoated telecommunication cable is about two times greater than the coefficient of friction of the low friction telecommunication cable.

18. The article of claim 14 , wherein the coefficient of friction of an uncoated telecommunication cable is more than three times greater than the coefficient of friction of the low friction telecommunication cable.

Assignees

• 3M Innovative Properties Co
• Yu Zhigang

Inventors

• Yu Zhigang
• Wang Yaming
• Cai Wei
• Jing Naiyong

Classifications

• C10N2040/32

  Wires, ropes or cables lubricants · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C09D7/67

  Particle size smaller than 100 nm · CPC title

• C10M133/38

  Heterocyclic nitrogen compounds · CPC title

• C09D5/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title