Serpentine fluid reactor components

Patent metadata

Field	Value
Publication number	US-10000706-B2
Application number	US-201615286627-A
Country	US
Kind code	B2
Filing date	Oct 6, 2016
Priority date	Dec 20, 2012
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

Some embodiments of the present invention provide components for a serpentine fluid reactor which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The components are designed by computer modeling the components individually and collectively in which the cross section of flow path is substantially circular under industrial conditions to validate the model design and its operation. Then iteratively the component designs are deformed and the operation of the deformed part(s) is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

First claim

What is claimed is:

1. A method to crack a gaseous hydrocarbon comprising passing the hydrocarbon through a reactor having a reduced calculated pressure drop across a flow path having a continuously smooth and differentiable perimeter and centerline of one or more first straight pipe sections of a serpentine reactor by not less than 10% relative to a second pipe section having a flow path having an ARQ from 1.0 to 1.02
where ARQ is defined as the ratio of aspect ratio (AR) to isoperimetric quotient (Q) of a section or segment of the flow passage perpendicular to the direction of flow (AR/Q)
and further where AR=Long/short and

Q
=

4
⁢
π
⁢

⁢
A

L
2

where A is area of a cross section of the flow path and L is the perimeter of the flow path comprising varying the flow passage over 90% of its length from 5% from the inlet and outlet so that the ARQ is from about 1.02 to about 1.15 at a temperature from 850° C. to 1000° C.

2. The method according to claim 1 , wherein the first pipe sections are part of a high pressure olefin polymerization reactor wherein the hydrocarbon comprises ethane.

3. The method according to claim 1 , wherein the first pipe section is part of the furnace tubes of an olefin cracker.

4. The method according to claim 3 , wherein over 90% of the flow passage does not change by more than 7% over an about 5% length of the flow path.

5. The method according to claim 4 , wherein the ARQ at one or more sections over said 90% of the length of the flow passage is from about 1.02 and about 1.12.

6. The method according to claim 5 , wherein the ARQ over said 80% of the length of the flow passage does not change by more than about 5% over an about 5% length of the flow path.

7. The method according to claim 6 , wherein the ARQ at one or more sections over said remaining about 80% of the length of the flow passage is from about 1.02 and about 1.15.

8. The method according to claim 7 , wherein the serpentine reactor has an increasing cross sectional area in the direction of flow such that the angle between the transverse normal vector and the pipe walls range from about 0° to about 85°.

9. The method according to claim 8 wherein the flow passage has a smooth curve in its longitudinal direction which although may change rapidly, does not include abrupt, sharp changes of internal section (steps) and a radius of curvature on the internal surface of the curve from unbound (straight) to half the vertical of the section radius.

10. The method according to claim 9 , wherein the first pipe section comprises from about 20 to about 50 weight % of chromium, about 25 to about 50 weight % of Ni, from about 1.0 to about 2.5 weight % of Mn less than about 1.0 weight % of niobium, less than about 1.5 weight % of silicon, less than about 3 weight % of titanium and all other trace metals and carbon in an amount less than about 0.75 weight % and from about 0 to about 6 weight % of aluminum.

11. The method according to claim 9 , wherein said first pipe section comprises from about 40 to about 65 weight % of Co; from about 15 to about 20 weight % of Cr; from about 20 to about 13 weight % of Ni; less than about 4 weight % of Fe and the balance of one or more trace elements and up to about 20 weight % of W the sum of the components adding up to 100 weight %.

12. The method according to claim 9 , wherein said first pipe section comprises from about 55 to about 65 weight % of Ni; from about 20 to about 10 weight % of Cr; from about 20 to about 10 weight % of Co; and from about 5 to about 9 weight % of Fe and the balance one or more of the trace elements.

13. The method according to claim 2 , wherein over said 90% of the flow passage does not change by more than about 7% over an about 5% length of the flow path.

14. The method according to claim 13 , wherein the ARQ at one or more sections over said 90% of the length of the flow passage is from about 1.02 and about 1.12.

15. The method according to claim 14 , wherein the ARQ over said about 80% of the length of the flow passage does not change by more than about 5% over an about 5% length of the flow path.

16. The method according to claim 15 , wherein the ARQ at one or more sections over said remaining about 80% of the length of the flow passage is from about 1.02 and about 1.15.

17. The method according to claim 16 , wherein the serpentine reactor has an increasing cross sectional area in the direction of flow such that the angle between the transverse normal vector and the pipe walls range from about 0° to about 85°.

18. The method according to claim 17 wherein the flow passage has a smooth curve in its longitudinal direction which although may change rapidly, does not include abrupt, sharp changes of internal section (steps) and a radius of curvature on the internal surface of the curve from unbound (straight) to half the vertical of the section radius.

19. The method according to claim 18 , wherein said first pipe section comprises from about 20 to about 50 weight % of chromium, about 25 to about 50 weight % of Ni, from about 1.0 to about 2.5 weight % of Mn less than about 1.0 weight % of niobium, less than about 1.5 weight % of silicon, less than about 3 weight % of titanium and all other trace metals and carbon in an amount less than about 0.75 weight % and from about 0 to about 6 weight % of aluminum.

20. The method according to claim 18 , wherein said first pipe section comprises from about 40 to about 65 weight % of Co; from about 15 to about 20 weight % of Cr; from about 20 to about 13 weight % of Ni; less than about 4 weight % of Fe and the balance of one or more trace elements and up to about 20 weight % of W the sum of the components adding up to 100 weight %.

21. The method according to claim 18 , wherein said first pipe section comprises from about 55 to about 65 weight % of Ni; from about 20 to about 10 weight % of Cr; from about 20 to about 10 weight % of Co; and from about 5 to about 9 weight % of Fe and the balance one or more of the trace elements.

Assignees

• Nova Chem Int Sa

Inventors

• Clavelle Eric
• Yajure Edgar
• Benum Leslie Wilfred
• Foy Edward Christopher
• Eisenhawer David

Classifications

• B01J19/243

  spirally, concentrically or zigzag wound · CPC title

• B01J2219/1943

  cylindrical · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C07C4/04

  Thermal processes {(C07C4/025 takes precedence)} · CPC title

• F16L43/002

  and formed from sheet having a circular passage · CPC title