Metallizable, scratch-resistant and solvent-resistant film

Patent metadata

Field	Value
Publication number	US-10000658-B2
Application number	US-201414900776-A
Country	US
Kind code	B2
Filing date	Jun 24, 2014
Priority date	Jun 27, 2013
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

The present invention relates to a coating composition comprising at least one thermoplastic acrylonitrile-butadiene-styrene copolymer in a content of at least 30% by weight of the solids content of the coating composition, at least one UV-curable reactive diluent in a content of at least 30% by weight of the solids content of the coating composition, at least one photoinitiator in a content of ≥0.1 to ≤10 parts by weight of the solids content of the coating composition and at least one organic solvent, where the proportion of ethylenically unsaturated groups is at least 3 mol per kg of the solids content of the coating composition. This is used to provide films and moldings coated therewith, having a metallizable, scratch-resistant and solvent-resistant surface.

First claim

The invention claimed is:

1. A coated film comprising a film of a thermoplastic polymer, a coating obtained by coating with a coating composition having a solids content and a content of ethylenically unsaturated groups comprising
(a) at least one then thermoplastic acrylonitrile-butadiene-styrene copolymer in a content of at least 30% by weight of the solids content of the coating composition, wherein the acrylonitrile-butadiene-styrene copolymer has an acrylonitrile content in the range from ≥19% to ≤35%;
(b) at least one UV-curable reactive diluent in a content of at least 30% by weight of the solids content of the coating composition;
(c) at least one photoinitiator in a content of ≥0.1 to ≤10 parts by weight of the solids content of the coating composition, and
(d) at least one organic solvent, comprising a mixture of 1-methoxy-2-propanol and at least 50% by weight of diacetone alcohol,
where the proportion of ethylenically unsaturated groups is at least 3 mol per kg of the solids content of the coating composition,
and a partial metal coating or a metal layer on the coated surface.

2. The coated film as claimed in claim 1 , comprising a polycarbonate film or a copolycarbonate film.

3. The coated film as claimed in claim 1 , wherein the acrylonitrile-butadiene-styrene copolymer (a) has an acrylonitrile content in the range from ≥20% to ≤30%.

4. The coated film as claimed in claim 1 , wherein the acrylonitrile-butadiene-styrene copolymer (a) has a polybutadiene content in the range from ≥10% to ≤16%.

5. The coated film as claimed in claim 1 , wherein the acrylonitrile-butadiene-styrene copolymer (a) has a Vicat softening temperature VET to ISO 306 of at least 95° C.

6. The coated film as claimed in claim 1 , wherein the at least one UV-curable reactive diluent (b) comprises bifunctional, trifunctional, tetrafunctional, pentafunctional and/or hexafunctional acrylic and/or methacrylic monomers.

7. The coated film as claimed in claim 1 , wherein the metal layer comprises at least one metal selected from the group consisting of tin, lead, silver, gold, palladium, platinum, cobalt, manganese, bismuth, copper, nickel, iron, chromium and mixtures thereof.

8. A method comprising utilizing the coated film coating composition as claimed in claim 1 for the production of 3D mouldings for the automotive, transport, electricals, electronics and construction industries in a film insert moulding process.

9. A moulded component comprising at least one coated film as claimed in claim 1 .

10. The coated film as claimed in claim 1 , wherein the acrylonitrile-butadiene-styrene copolymer (a) has an acrylonitrile content in the range from ≥20% to ≤30%, and wherein the acrylonitrile-butadiene-styrene copolymer (a) has a polybutadiene content in the range from ≥10% to ≤16%.

11. A process for producing the coated film as claimed in claim 1 , comprising the steps of:
(i) coating a film with a coating composition having a solids content and a content of ethylenically unsaturated groups comprising
(a) at least one thermoplastic acrylonitrile-butadiene-styrene copolymer in a content of at least 30% by weight of the solids content of the coating composition, wherein the acrylonitrile-butadiene-styrene copolymer has an acrylonitrile content in the range from ≥19% to ≤35%;
(b) at least one UV-curable reactive diluent in a content of at least 30% by weight of the solids content of the coating composition;
(c) at least one photoinitiator in a content of ≥0.1 to ≤10 parts by weight of the solids content of the coating composition; and
(d) at least one organic solvent, comprising a mixture of 1-methoxy-2-propanol and at least 50% by weight of diacetone alcohol,
where the proportion of ethylenically unsaturated groups is at least 3 mol per kg of the solids content of the coating composition;

(ii) drying the coating;
(iii) optionally cutting the film to size and/or printing and/or thermally or mechanically forming the film;
(iv) irradiating the coating with UV radiation to cure the coating;
(v) coating the cured coating with a metal coating.

Assignees

• Covestro Deutschland Ag

Inventors

• Kostromine Serguei
• Petzoldt Joachim
• Künzel Roland
• Leonhardt Konstantin

Classifications

• C08J7/0423

  with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08L2205/04

  containing interpenetrating networks · CPC title

• C09D7/20

  Diluents or solvents · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title