Carbon monoxide shift reaction apparatus and carbon monoxide shift conversion method

Patent metadata

Field	Value
Publication number	US-10000378-B2
Application number	US-201414768909-A
Country	US
Kind code	B2
Filing date	Feb 18, 2014
Priority date	Feb 21, 2013
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

A carbon monoxide (CO) Shift reaction apparatus and a CO shift conversion method are capable of increasing the service life of a CO shift catalyst and reducing loss of energy. The CO shift reaction apparatus includes a plurality of CO shift reaction units in which a plurality of CO shift catalysts haying mutually different active-temperature regions are arranged in a gas flow direction.

First claim

The invention claimed is:

1. A CO shift reaction apparatus comprising a CO shift reaction unit including a plurality of CO shift catalysts with mutually different active-temperature regions arranged in a gas flow direction,
wherein the CO shift reaction unit is a CO shift reactor of one stage having a Ni—Mo catalyst and a Co—Mo catalyst, and
wherein the Ni—Mo catalyst is arranged in an upstream portion of the CO shift reaction unit as the CO shift catalyst and the Co—Mo catalyst is arranged in a downstream portion of the CO shift reaction unit as the CO shift catalyst.

2. The CO shift reaction apparatus according to claim 1 , wherein a plurality of the CO shift reaction units is serially arranged.

3. The CO shift reaction apparatus according to claim 2 , further comprising a heat exchanger configured to cool gas after a shift reaction in the CO shift reaction unit to a temperature within a range of 150 to 300° C.

4. The CO shift reaction apparatus according to claim 3 , further comprising a second CO shift reaction unit arranged in an upstream of the heat exchanger,
wherein the second CO shift reaction unit is a CO shift reactor of one stage having a Ni—Mo catalyst and a Co—Mo catalyst, and
wherein the Ni—Mo catalyst is arranged in an upstream portion of the second CO shift reaction unit and the Co—Mo catalyst is arranged in a downstream portion of the second CO shift reaction unit.

5. The CO shift reaction apparatus according to claim 2 , wherein the Ni—Mo catalyst includes molybdenum (Mo) and nickel (Ni) which are carried by one or more of titanium (Ti), zirconium (Zr), and cerium (Ce).

6. The CO shift reaction apparatus according to claim 5 , wherein the Co—Mo catalyst includes CoO and MoO 3 carried by Al 2 O 3 or MoO.

7. The CO shift reaction apparatus according to claim 2 further comprising a line for circulating unreacted gas provided between the CO shift reaction units.

8. The CO shift reaction apparatus according to claim 2 , wherein the CO shift reaction unit is configured to control the temperature of the upstream portion of the unit within a range of 150 to 300° C. and is configured to control the temperature of the downstream portion of the unit within a range of 300 to 500° C.

Assignees

• Mitsubishi Heavy Ind Ltd

Inventors

• Abe Hyota
• Seiki Yoshio
• Sawata Akihiro
• Tanaka Yukio
• Yonemura Masanao

Classifications

• C01B3/16 Primary

  using catalysts · CPC title

• C01B2203/0288

  containing two CO-shift steps · CPC title

• B01J23/882

  and cobalt · CPC title

• C01B2203/1058

  Nickel catalysts · CPC title

• C01B2203/0883

  by indirect heat exchange · CPC title